GCMS calibration data for volatile organic compounds, May 2002

NYC 9/11 Public Portal Document

Data File C:\HPCHEM\1\DATA\MAY0 6 0 2\CAL8 0A.D Vial: 2 Acq On 7 May 2002 6:45 pm Operator: Sample GC/MS SCAN 4/29 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 9 9:36 2002 Quant Results File: GCMS0507.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0507.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue May 07 08:24:38 2002 Response via : Initial Calibration DataAcq Meth : GCMS0507

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.19 152 483132 40.00 ug/1 0.00 10) Naphthalene-d8 15.83 136 1767277 40.00 ug/1 0.00 17) Acenaphthene-diO 21.14 164 960962 40.00 ug/1 0.00 30) Phenanthrene-diO 25.58 188 1333949 40.00 ug/1 0.00 38) Chrysene-dl 2 33.65 240 808913 40.00 ug/1 0.00 44) Perylene-dl2 37.87 264 491990 40.00 ug/1 0.00

System Monitoring Compounds 28) TCMX 23.28 209 45070 9.43 ug/L 0.00 Spiked Amount 10.000 Recovery = 94.30%

Target Compounds S -/ Qvalue 2) N-nitroso-dimethyl amine 5.84 74 956269 78.58 ug/1 98 3) bis(2-Chloroethyl)ether 11.59 93 1242349 78.72 ug/1 97 4) 1,3-Dichlorobenzene 12.09 146 1180349 78.84 ug/1 99 5) 1,4-Dichlorobenzene 12.24 146 1295636 79.10 ug/1 99 6) 1,2-Dichlorobenzene 12.75 146 1128211 79.14 ug/1 99 7) 2,21-oxybis(1-Chloropropan 13.07 45 2388955 78.07 ug/1 98 8) N-Nitroso-di-n-propylamine 13.47 70 889818 78.91 ug/1 98 9) Hexachloroethane 13.61 117 464817 79.76 ug/1 92 11) Nitrobenzene 13.88 77 1150593 80.19 ug/1 97 12) Isophorone 14.53 82 2235399 79.48 ug/1 96 13) bis(2-Chloroethoxy)methane 15.21 93 1454099 79.80 ug/1 99 14) 1,2,4-Trichlorobenzene 15.72 180 981573 80.00 ug/1 99 15) Naphthalene 15.90 128 2885608 79.35 ug/1 99 16) Hexachlorobutadiene 16.44 225 459108 80.83 ug/1 100 18) Hexachlorocyclopentadiene 18.63 237 390967 80.28 ug/1 100 19) 2-Chloronaphthalene 19.40 162 1655993 78.88 ug/1 98 20) Dimethylphthalate 20.50 163 2069680 78.29 ug/1 100 21) 2,6-Dinitrotoluene 20.72 165 469228 82.99 ug/1 93 22) Acenaphthylene 20.67 152 2936739 78.50 ug/1 99 23) Acenaphthene 21.24 153 1748457 78.41 ug/1 100 24) 2,4-Dinitrotoluene 21.88 165 516040 84.68 ug/1 91 25) Diethylphthalate 22.63 149 1855624 78.38 ug/1 100 26) 4-Chlorophenyl-phenylether 22.78 204 937422 80.10 ug/1 98 27) Fluorene 22.76 166 1849170 78.64 ug/1 100 29) Azobenzen/ 1,2-Diphenylhyd 23.25 77 2241778 76.48 ug/L 96 31) N-Nitrosodiphenylamine 23.17 168 667215 80.07 ug/1 93 32) 4-Bromophenyl-phenylether 24.24 248 533146 80.82 ug/1 96 33) Hexachlorobenzene 24.68 284 613598 81.41 ug/1 97 34) Phenanthrene 25.66 178 2544830 79.51 ug/1 100

(#) = qualifier out of range (m) = manual integration CAL80A.D GCMS0507.M Thu May 09 09:36:18 2002 Page 1

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