GCMS reference analysis results, DEP Box 25, May 1 2002

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Data File C:\HPCHEM\l\DATA\MAY0102\REF2.D Vial: 9 Acq On 1 May 2002 3:23 pm Operator : Sample gc/ms scan 4/18 Inst : 209 Mise ' Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 2 11:40 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration DataAcq Meth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.20 152 448911 40.00 ug/1 -0.01 10) Naphthalene-d8 15.84 136 1654253 40.00 ug/1 -0.01 17) Acenaphthene-diO 21.15 164 876906 40.00 ug/1 0.00 30) Phenanthrene-diO 25.58 188 1265290 40.00 ug/1 -0.01 38) Chrysene-dl2 33.65 240 873282 40.00 ug/1 -0.02 44) Perylene-dl2 37.87 264 553471 40.00 ug/1 -0.01

System Monitoring Compounds 2 8) TCMX 23.28 209 35374 8.29 ug/L -0.01 Spiked Amount 10.000 Recovery = 82.90%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.85 74 144107 11.74 ug/1 96 3) bis (2-Chloroethyl') ether 11.60 93 284959 17.90 ug/1 99 4) 1,3-Dichlorobenzene 12.10 146 168009 12.01 ug/1 100 5) 1,4-Dichlorobenzene 12.25 146 184074 12.04 ug/1 100 6) 1,2-Dichlorobenzene 12.76 146 188354 14.21 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.08 45 597362 18.15 ug/1 100 8) N-Nitroso-di-n-propylamine 13.47 70 225190 18.87 ug/1 99 9) Hexachloroethane 13.61 117 37170 6.47 ug/1 98 11) Nitrobenzene 13.89 77 256938 17.05 ug/1 100 12) Isophorone 14.53 82 451959 15.47 ug/1 99 13) bis(2-Chloroethoxy)methane 15.22 93 339520 18.32 ug/1 100 14) 1,2,4-Trichlorobenzene 15.72 180 154876 13.82 ug/1 99 15) Naphthalene 15.90 128 635468 18.35 ug/1 100 16) Hexachlorobutadiene 16.44 225 27419 5.33 ug/1 98 18) Hexachlorocyclopentadiene 18.64 237 4603 1.04 ug/1 97 19) 2-Chloronaphthalene 19.40 162 378881 19.57 ug/1 100 20) Dimethylphthalate 20.49 163 481316 19.53 ug/1 99 21) 2,6-Dinitrotoluene 20.71 165 90295 16.86 ug/1 99 22) Acenaphthylene 20.67 152 580142 16.65 ug/1 100 23) Acenaphthene 21.24 153 396809 19.41 ug/1 100 24) 2,4-Dinitrotoluene 21.87 165 104180 18.14 ug/1 98 25) Diethylphthalate 22.62 149 478777 21.41 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 193655 18.31 ug/1 98 27) Fluorene 22.75 166 443930 20.37 ug/1 99 29) Azobenzen/ 1,2-Diphenylhyd 23.25 77 557952 18.57 ug/L 98 31) N-Nitrosodiphenylamine 23.16 168 133576 15.92 ug/1 95 32) 4-Bromophenyl-phenylether 24.24 248 108419 17.64 ug/1 97 33) Hexachlorobenzene 24.68 284 127071 18.51 ug/1 94 34) Phenanthrene 25.66 178 601760 19.62 ug/1 99

(#) = qualifier out of range (m) = manual integration REF2.D GCMS0501.M Thu May 02 11:43:39 2002 Page 1

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