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GCMS analysis results for sample AE06455, April 2002

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Laboratory report documenting GCMS analysis of sample AE06455 conducted on April 19, 2002, by the DEP.

NYC-WTC_000039588–000039610

Folder label: “GCMS X 3/19/02 A 4/17/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\APR1702\6455.D Vial: 13 Acq On : 17 Apr 2002 7:57 pm Operator: Sample : gc/ms scan 3/19 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 8 Benzoic acid, 4-ethoxy-, ethyl Concentration Rank 12 R.T. EstConc Area Relative to ISTD R.T. 21.56 0.45 ug/1 72115 Acenaphthene-dl0 21.15 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzoic acid, 4-ethoxy-, ethyl este 194 C11H1403 023676-09-7/ 96 2 Ethylparaben 166 C9H10O3 000120-47-8-58 ■ 3 1-Butanone, 4-chloro-l- (4-hydroxyph 198 C10H11C1O2 007150-55-2 38 4 Paroxypropione 150 C9H10O2 000070-70-2 38 /.bundance Scan 1799 (21.558 min): 6455.D (-) m/z 120.95 100.00%) 121

149 5000 138 194 65 93 166 IIE ' I 1 ' ' ' 1 1 39 21.20 21.40 21.60 21.80 50J 77 HIT TT‘ — 11111' r TTTT 1’11 ■ i" ‘11 ■ TITTTT m/ z 149.00 54.14% m/z-> :20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance। #21260: Benzoic acid, 4-ethoxy-, ethyl ester 121

149 5000 21.20 21.40 21.60 21.80 138 194 m/z 194.05 30.96% 27 65 93 166

m/z-> I 1 r 1'1 r ■ ■' i ■'1 ‘ r '11111" r " ■ r TTITTTTTTTTTTT — I’T 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 HH ’ 1’11111

Abundance #13954: Ethylparaben 121 ' । 1 1 ■ 1 । 1 ' 1 ■ r1 1 ' ■ । ' 1 1 1 । 1 21.20 21.40 21.60 21.80 5000- m/z 137.95 25.22%| 65 93 138 166

mtz-> TT r 1" I ! 11 53 11 #4 T X I""I""I u i'"' r'1' i" " i 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #22266: 1-Butanone, 4-chloro-1 -(4-hydroxyphenyl)- 1 i 1 ' 1 ' 1 1 1 ' 1 1 1 ' 1 1 । 1 * 1 * । ■ 121 21.20 21.40 21.60 21.80 m/z 64.95 16.48%|

5000 136 65 93 ...... 41 53—177 X TTTTT 162 198 I [ i t I | | i i i r । I i i i | i i i i | i i i i | i i i I | i i i f i ■ ■ ■ ■ । • ■ ■ ■ । • ■ ■ ■ । । i i । [ । m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 21.20 21.40 21.60 21.80

6455.D GCMS0412.M Thu Apr 18 09:14:19 2002 Page 8

NYC-WTC_000039602

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NYC-WTC_000039602Source: NYC Law Department, mirrored locally

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