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GCMS analysis results for sample AE03804, March 22, 2002

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Laboratory report detailing gas chromatography-mass spectrometry analysis of sample AE03804 conducted on March 22, 2002.

NYC-WTC_000037948–000037963

Folder label: “GCMS X 2/20/02 A 3/20/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\031902\3804.D Vial: 14 Acq On : 19 Mar 2002 10:18 pm Operator: McLean Sample : RE-INJ 2/20 Inst ; Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 5 SILICATE ANION TETRAMER Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

20.28 0.93 ug/L 427084 Acenaphthene-dl0 18.13

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 SILICATE ANION TETRAMER 883 C24H72012Si12 000000-00-0 50 2 3,4-DIHYDROXYMANDELIC ACID-TETRATMS 472 C20H4005Si4 000000-00-0 40 3 n-Nonadecanoic acid, pentamethyl... 428 C24H5202Si2 000000-00-0 35 4 Benzeneethanamine, N-[(pentafluo... 563 C24H34F5NO3Si3 055429-13-5 35 Abundance Scan 1897 (20.282 min): 3804.D (-) m/z 73.10 100.00% 73

5000 355 147 221 —1PPTPP 281

m/z-> 45 ■;< 117 191, , 249, I 191 0- - TTT TPr ■ . 1 114- 50 100 150 200 250 300 327 350 400 , 101 — 450 20.00 20.20 20.40 20.60 m/z 355.10 32.38%

Abundance #391009: SILICATE ANION TETRAMER 73

5000 147 — i I 20.00 20.20 20.40 20.60 221 m/z 147.10 25.94%

m/z-> 0- A2 28 — , 100 150 1200 250 50 281 —r —I 300 350 401 400 450 Abundance #361636: 3,4-DIHYDROXYMANDELIC ACID-TETRATMS 73 . ...... PA 20.00 20.20 20.40 20.60 355 m/z 221.10 23.02% 5000

45 147 193 267295 429457 0- ■ ‘i 1 1 • i • TTT 1Brmm1*rma*TTT m/z-> 50100 150 200 250 300 350 400 450 Abundance #346318: n-Nonadecanoic acid, pentamethyldisilyl ester 43 73 355 -A....... 20.00 20.20 20.40 20.60 m/z 281.00 15.08%

147 5000 413 203

rn/z-> 0- ul L 50 100 150 200 245 295 325 j IIm ------ 250 300 350 400 450 T — 20.00 20.20 20.40 20.60 T

onA EAOAOAO M ‘T1-4 IA0.n0 onno Dace 7

NYC-WTC_000037959

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NYC-WTC_000037959Source: NYC Law Department, mirrored locally

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