GCMS reference standard results for volatile organics, Mar 2002

NYC 9/11 Public Portal Document

5 Quantitation Report (QT Reviewed)

. Data File : C:\MSDCHEM\1\DATA\031202\REFC0312.D Vial: 51 Acq On : 12 Mar 2002 9:51 pm Operator: McLean Sample : REF 3 2/19/02 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 15 13:53:19 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 150 1761791 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 4691253 20.00 ug/L 0.00 17) Acenaphthene-dl0 18.14 164 2640021 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 4150705 20.00 ug/L 0.00 38) Chrysene-dl2 30.32 240 3946616 20.00 ug/L 0.00 44) Perylene-dl2 34.20 264 2672363 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 302203 6.10 ug/L 0.00 Spiked Amount 5.000 Recovery = 122.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.58 74 201483 5.09 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 569278 9.13 ug/L 82 4) 1,3 - Dichlorobenze 9.38 146 320330 5.19 ug/L 96 5) 1,4 - Dichlorobenzene 9.59 146 352553 5.73 ug/L 97 6) 1,2 - Dichlorobenzene 9.96 146 361011 6.34 ug/L 98 7) 2,2 ' - oxybis (l-Chloropr 10.43 45 1275850 8.98 ug/L 98 8) N-Nitroso-di-n-propylamine 10.76 70 463311 10.33 ug/L 96 9) Hexachloroethane 10.86 117 72872 3.15 ug/L 100 11) Nitrobenzene 11.10 77 577574 6.84 ug/L 95 12) Isophorone 11.81 82 1304127 8.39 ug/L 100 13) bis(2-Chloroethoxy) methan 12.55 93 714375 7.63 ug/L 98 14) 1,2,4-Trichlorobenzene 12.90 180 320501 5.97 ug/L 98 15) Naphthalene 13.08 12 S 1495442 7.67 ug/L 99 16) Hexachlorobutadiene 13.53 225 47672 1.59 ug/L 97 18) Hexachlorocyclopentadiene 15.61 237 23622 1.02 ug/L 95 19) 2-chloronaphthalene 16.51 162 838501 6.96 ug/L 98 20) Dimethylphthalate 17.60 163 1202812 8.36 ug/L 100 21) 2,6-Dinitrotoluene 17.71 165 226475 7.40 ug/L 91 22) Acenaphthylene 17.70 152 1423689 8.52 ug/L 100 2 3) Acenaphthene 18.22 153 910780 8.01 ug/L 99 24) 2,4-Dinitrotoluene 18.85 165 318689 7.27 ug/L 97 25) Diethylphthalate 19.73 149 1160925 9.38 ug/L 97 26) 4-Chlorophenyl-phenyl ethe 19.89 204 539486 8.18 ug/L 98 27) Fluorene 19.76 166 1170047 8.73 ug/L 98 28) Azobenzen/ 1,2-Diphenylhyd 20.35 77 1424000 7.80 ug/L 97 30) N-Nitrosodiphenylamine 20.26 169 749530 8.40 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.32 248 312846 3.54 ug/L 93 32) Hexachlorobenzene 21.34 284 315581 8.17 ug/L 98 33) Phenanthrene 22.56 178 1687305 8.78 ug/L 99 3 4) Anthracene 22.70 178 1645042 8.62 ug/L 100 35) Di-n-butylphthalate 24.65 149 2011252 9.13 ug/L 99 36) Fluoranthene 26.06 202 1930931 8.84 ug/L 99 39) Pyrene 26.69 202 20475.89 7.50 ug/L 97 40) Butylbenzylphthalate 29.05 149 866613 7.42 ug/L 98 41) Benzo (a) antracene 30.29 228 1646721 7.95 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.91 149 1227560 7.95 ug/L 97 43) Chrysene 30.39 228 1735554 8.82 ug/L 98 45) Di-n-Octylphthalate 32.76 149 1843113 6.42 ug/L 98 46) Benzo (b) fluoranthene 33.23 252 1544808 8.20 ug/L 99

(#) = qualifier out of range (m) = manual integration REFCO312.D 5030302.M Fri Mar 15 13:57:16 2002 Page 1

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