GCMS reference standard data, Mar 15 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

. Data File : C:\MSDCHEM\1\DATA\031202\REFB0312 .D Vial: 27 Acq On : 12 Mar 2002 10:06 am Operator: McLean Sample : REFB 2/19/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 15 10:10:21 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.55 150 1393144 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3609625 20.00 ug/L 0.00 17) Acenaphthene-diO 18.14 164 2032470 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 3149385 20.00 ug/L 0.00 38) Chrysene-dl2 30.32 240 2917588 20.00 ug/L 0.00 44) Perylene-dl2 34.19 264 1495678 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.44 235 288000 7.67 ug/L 0.00 Spiked Amount 5.000 Recovery = 153.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.58 74 191653 6.13 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 558456 11.32 ug/L 82 4) 1,3 - Dichlorobenze 9.38 146 351139 7.20 ug/L 99 5) 1,4 - Dichlorobenzene 9.59 146 363303 7.47 ug/L 97 6) 1,2 - Dichlorobenzene 9.97 146 365992 8.13 ug/L 100 7) 2,2 1 - oxybis (l-Chloropr 10.43 45 1256136 11.18 ug/L 98 8) N-Nitroso-di-n-propylamine 10.76 70 453729 12.80 ug/L 95 9) Hexachloroethane 10.86 117 108238 5.92 ug/L 94 11) Nitrobenzene 11.10 77 591702 9.10 ug/L 98 12) 1sophorone 11.82 82 1299385 10.86 ug/L 99 13) bis(2-Chloroethoxy) methan 12.56 93 725623 10.08 ug/L 98 14) 1,2,4-Trichlorobenzene 12.90 180 325074 7.87 ug/L 96 15) Naphthalene 13.08 128 1442123 9.61 ug/L 100 16) Hexachlorobutadiene 13.53 225 96865 4.19 ug/L 98 18) Hexachlorocyclopentadiene 15.61 237 37807 2.11 ug/L 99 19) 2-chloronaphthalene 16.51 162 828775 8.93 ug/L 99 20) Dimethylphthalate 17.60 163 1219555 11.01 ug/L 99 21) 2,6-Dinitrotoluene 17.71 165 22'9179 9.72 ug/L 93 22) Acenaphthylene 17.70 ■ 152 1394630 10.83 ug/L 100 23) Acenaphthene 18.22 153 911873 10.42 ug/L 99 24) 2,4-Dinitrotoluene 18.86 165 323790 9.59 ug/L 94 25) Diethylphthalate 19.73 149 1179846 12.38 ug/L 98 26) 4-Chlorophenyl-phenyl ethe 19.90 204 541750 10.67 ug/L 97 27) Fluorene 19.77 166 1172756 11.37 ug/L 100 28) Azobenzen/ 1,2-Diphenylhyd 20.35 77 1419717 10.10 ug/L 98 30) N-Nitrosodiphenylamine 20.26 169 690317 10.20 ug/L 98 31) 4-Bromophenyl-phenyl ether 21.33 248 308221 11.09 ug/L 98 32) Hexachlorobenzene 21.35 284 333477 11.37 ug/L 91 33) Phenanthrene 22.56 178 1716504 11.77 ug/L 99 34) Anthracene 22.71 178 1608205 11.11 ug/L 100 35) Di-n-butylphthalate 24.65 149 2201347 13.17 ug/L 99 36) Fluoranthene 26.06 202 1977409 11.93 ug/L 99 39) Pyrene 26.69 202 2082858 10.33 ug/L 95 4 0) Butylbenzylphthalate 29.05 149 897956 10.40 ug/L 96 41) Benzo (a) antracene 30.29 228 1653565 10.80 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.92 149 1266761 11.10 ug/L 97 43) Chrysene 30.39 228 1739136 11.95 ug/L . 98 45) Di-n-Octylphthalate 32.75 149 1829528 11.39 ug/L 98 46) Benzo (b) fluoranthene 33.23 252 1253814 11.90 ug/L 98

(#) = qualifier out of range (m) = manual integration REFB0312.D 5080302.M Fri Mar 15 10:13:28 2002 Page 1

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