GCMS reference results, sample AE05914, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

•Data File ;•C:\MSDCHEM\l\DATA\032202\REFBJ322.D vial: 7 Acq On : 23 Mar 2002 12:16 am Operator: McLean Sample : REF 2 3/14/02 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Apr 05 07:40:42 2002 Quant Results File: 5080302.RES

■Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Wed Mar 27 06:57:36 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.55 150 1347189 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3684017 20.00 ug/L 0.00 17) Acenaphthene-dlO 18.14 164 2090544 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.50 188 3219527 20.00 ug/L 0.00 38) Chrysene-dl2 30.32 240 2803045 20.00 ug/L 0.00 44) Perylene-dl2 34.18 264 1464176 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-DDD (SURR) 27.43 235 208468 5.43 ug/L 0.00 Spiked Amount 5.000 Recovery = 108.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 107324 3.55 ug/L # 100 3) bis(2-chloroethyl) ether 8.98 93 460464 9.66 ug/L 81 4) 1,3 - Dichlorobenze 9.38 146 358218 7.59 ug/L 99 5) 1,4 - Dichlorobenzene 9.60 146 370586 7.88 ug/L 97 6) 1,2 - Dichlorobenzene 9.97 146 369882 8.49 ug/L 99 7) 2,2 ' - oxybis (1-Chloropr 10.43 45 1097061 10.10 ug/L 98 8) N-Nitroso-di-n-propylamine 10.75 70 341955 9.97 ug/L 95 9) Hexachloroethane 10.86 117 139568 7.90 ug/L 91 11). Nitrobenzene 11.10 77 454500 6.85 ug/L 99 12) Isophorone 11.82 82 1032496 8.46 ug/L 99 13) bis(2-Chloroethoxy) methan 12.56 93 582415 7.93 ug/L 98 14) 1,2,4-Trichlorobenzene 12.90 180 320221 7.59 ug/L 98 ■ 15) Naphthalene 13.08 128 1304314 8.52 ug/L 100 16) Hexachlorobutadiene 13.53 225 132867 5.63 ug/L 99 18) Hexachlorocyclopentadiene 15.61 237 21571 1.17 ug/L 94 19) 2-chloronaphthalene 16.51 162 689146 7.22 ug/L 100 20) Dimethylphthalate 17.59 163 1034417 9.08 ug/L 97 21) 2,6-Dinitrotoluene 17.70 165 179421 7.40 ug/L 99 22) Acenaphthylene 17.69 152 1133442 8.56 ug/L 98 23) Acenaphthene 18.23 153 786460 8.74 ug/L 98 24) 2,4-Dinitrotoluene 18.86 165 244944 7.06 ug/L 96 25) Diethylphthalate 19.72 149 988903 10.09 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.90 204 451619 8.64 ug/L 97 27) Fluorene 19.76 166 982987 9.26 ug/L 97 28) Azobenzen/ 1,2-Diphenylhyd 20.34 77 1240786 8.58 ug/L 98 30) N-Nitrosodiphenylamine 20.26 169 477260 6.90 ug/L 97 31) 4-Bromophenyl-phenyl ether 21.32 248 259111 9.12 ug/L 89 32) Hexachlorobenzene 21.34 284 266670 8.90 ug/L 96 33) Phenanthrene 22.56 178 1370867 9.19 ug/L 100 34) Anthracene 22.71 178 1234068 8.34 ug/L 100 35) Di-n-butylphthalate 24.65 149 1741063 10.19 ug/L 99 36) Fluoranthene 26.06 202 1533174 9.05 ug/L 98 39) Pyrene 26.69 202 1611208 8.31 ug/L 98 40) Butylbenzylphthalate 29.05 149 678843 8.18 ug/L 97 41) Benzo (a) antracene 30.29 228 1144236 7.78 ug/L 98 42) Bis (2-ethylhexyl) phthala 30.91 149 856551 7.81 ug/L 94 43) Chrysene 30.38 228 1169689 8.37 ug/L 98 45) Di-n-Octylphthalate 32.76 149 1139721 7.25 ug/L 99 46) Benzo (b) fluoranthene 33.23 252 848631 8.22 ug/L 98

(#) = qualifier out of range (m) = manual integration REFBJ322.D 5080302.M Fri Apr 05 07:40:51 2002 Page 1

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