GCMS reference results, sample AE05914, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\l\DATA\032202\REFAJ322.D Vial: 6 Acq On : 22 Mar 2002 11:28 pm Operator: McLean Sample : REF 1 3/14/02 Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Apr 05 07:40:14 2002 Quant Results File: 5080302.RES

Quant Method C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title Quantitation For Method 508gcscan Last Update Wed Mar 27 06:57:36 2002 Response via Initial Calibration DataAcq Meth 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.55 150 1684188 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 4662333 20.00 ug/L 0.00 17) Acenaphthene-dlO 18.14 164 2626604 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.50 188 4035876 20.00 ug/L 0.00 38) Chrysene-dl2 30.32 240 3379491 20.00 ug/L 0.00 44) Perylene-dl2 34.18 264 1824683 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-DDD (SURR) 27.43 235 221541 4.60 ug/L 0.00 Spiked Amount 5.000 Recovery = 92.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.61 74 77751 2.06 ug/L # 100 3) bis(2-chloroethyl) ether 8.98 93 330774 5.55 ug/L 81 4) 1,3 - Dichlorobenze 9.38 146 249259 4.23 ug/L 99 5) 1,4 - Dichlorobenzene 9.60 146 258012 4.39 ug/L 96 6) 1,2 - Dichlorobenzene 9.97 146 260461 4.78 ug/L 98 7) 2,2 ' - oxybis (1-Chloropr 10.43 45 819723 6.04 ug/L 99 8) N-Nitroso-di-n-propylamine 10.75 70 288241 6.72 ug/L 98 9) Hexachloroethane 10.86 117 97518 4.41 ug/L 91 11) Nitrobenzene 11.11 77 302031 3.60 ug/L 95 12) Isophorone 11.82 82 793180 5.13 ug/L 99 13) bis(2-Chloroethoxy) methan 12.56 93 448400 4.82 ug/L 99 14) 1,2,4-Trichlorobenzene 12.90 180 236042 4.42 ug/L 97 15) Naphthalene 13.08 128 1001041 5.17 ug/L 99 16) Hexachlorobutadiene 13.53 225 100016 3.35 ug/L 95 18) Hexachlorocyclopentadiene 15.61 237 12158 0.53 ug/L 93 19) 2-chloronaphthalene 16.51 162 669360 5.58 ug/L 98 20) Dimethylphthalate 17.60 163 1057459 7.39 ug/L 100 21) 2,6-Dinitrotoluene 17.70 165 182308 5.98 ug/L 97 22) Acenaphthylene 17.70 152 1090678 6.56 ug/L 98 23) Acenaphthene 18.23 153 758236 6.70 ug/L 98 24) 2,4-Dinitrotoluene 18.86 165 241119 5.53 ug/L 94 25) Diethylphthalate 19.72 149 1049355 8.52 ug/L 98 26) 4-Chlorophenyl-phenyl ethe 19.90 204 467358 7.12 ug/L 96 27) Fluorene 19.76 166 1014403 7.61 ug/L 98 28) Azobenzen/ 1,2-Diphenylhyd 20.34 77 1322422 7.28 ug/L 95 30) N-Nitrosodiphenylamine 20.27 169 537107 6.19 ug/L 98 31) 4-Bromophenyl-phenyl ether 21.32 248 266507 7.48 ug/L 90 32) Hexachlorobenzene 21.35 284 282364 7.51 ug/L 94 33) Phenanthrene 22.56 178 1457035 7.80 ug/L 99 34) Anthracene 22.70 178 1326076 7.15 ug/L 98 35) Di-n-butylphthalate 24.65 149 1850823 8.64 ug/L 99 36) Fluoranthene 26.06 202 1628743 7.67 ug/L 96 39) Pyrene 26.69 202 1679789 7.19 ug/L 99 40) Butylbenzylphthalate 29.06 149 729371 7.29 ug/L 97 41) Benzo (a) antracene 30.29. 228 1203271 6.78 ug/L 96 42) Bis (2-ethylhexyl) phthala 30.91 149 932873 7.05 ug/L. 100 43) Chrysene 30.38 228 1284033 7.62 ug/L 97 45) Di-n-Octylphthalate 32.76 149 1242260 6.34 ug/L 97 46) Benzo (b) fluoranthene 33.23 252 917559 7.14 ug/L 97

(#) = qualifier out of range (m) = manual integration REFAJ322.D 5080302.M Fri Apr 05 07:40:33 2002 Page 1

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