GCMS reference standard data, Mar 15 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

. Data File : C:\MSDCHEM\1\DATA\031202\REFA0312 .D Vial: 26 Acq On : 12 Mar 2002 8:54 am Operator: McLean Sample : REFI 2/19/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 15 10:03:53 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 r 9.55 150 1397749 20.00 ug/L 0.00 10) Naphthalene-d8 VS 13.03 136 3604775 20.00 ug/L 0.00 17) Acenaphthene-diO n 18.14 164 2056377 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.50 188 3192671 20.00 ug/L 0.00 38) Chrysene-dl2 ar 30.32 240 3042388 20.00 ug/L 0.00 44) Perylene-dl2 a4 34-19 264 1852348 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.44 235 260447 6.84 ug/L 0.00 Spiked Amount 5.000 Recovery = 136.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 201789m 6.43 ug/L 3) bis(2-chloroethyl) ether 8.98 93 497777 10.06 ug/L 83 4) 1,3 - Dichlorobenze 9.38 146 341059 6.97 ug/L 96 5) 1,4 - Dichlorobenzene 9.59 146 356408 7.30 ug/L 97 6) 1,2 - Dichlorobenzene 9.97 146 347223 7.69 ug/L 94 7) 2,2 ' - oxybis (l-Chloropr 10.43 45 1127335 10.00 ug/L 98 8) N-Nitroso-di-n-propylamine 10.76 70 418454m 11.76 ug/L 9) Hexachloroethane 10.86 117 109727 5.98 ug/L 99 11) Nitrobenzene 11.10 77 518239 7.98 ug/L 98 12) 1sophorone 11.82 82 1154888 9.67 ug/L 98 13) bis(2-Chloroethoxy) methan 12.55 93 626479 8.71 ug/L 100 14) 1,2,4-Trichlorobenzene 12.91 180 303007 7.34 ug/L 98 15) Naphthalene 13.08 128 1329932 8.88 ug/L 99 16) Hexachlorobutadiene 13.53 225 107479 4.66 ug/L 95 18) Hexachlorocyclopentadiene 15.61 237 32989 1.82 ug/L 94 19) 2-chloronaphthalene 16.51 162 757137 8.07 ug/L 99 20) Dimethylphthalate 17.60 163 1116462 9.96 ug/L 99 21) 2,6-Dinitrotoluene 17.71 165 209483 8.78 ug/L 94 2 2) Acenaphthylene 17.70 152 1263806 9.70 ug/L 100 23) Acenaphthene 18.22 153 842249 9.51 ug/L 100 24) 2,4-Dinitrotoluene 18.86 165 298510 8.74 ug/L 93 25) Diethylphthalate 19.73 149 1079000 11.19 ug/L 98 26) 4-Chlorophenyl-phenyl ethe 19.90 204 493080 9.59 ug/L 98 27) Fluorene 19.76 166 1087647 10.42 ug/L 100 28) Azobenzen/ 1,2-Diphenylhyd 20.35 77 1312091 9.23 ug/L 98 30) N-Nitrosodiphenylamine 20.26 169 664289 9.68 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.32 248 296206 10.51 ug/L 97 3 2) Hexachlorobenzene 21.34 284 302514 10.18 ug/L 97 33) Phenanthrene 22.56 178 1556284 10.52 ug/L 100 34) Anthracene 22.71 178 1514952 10.32 ug/L 99 35) Di-n-butylphthalate 24.65 149 1998122 11.79 ug/L 99 3 6) Fluoranthene 26.06 202 1823409 10.85 ug/L 100 39) Pyrene 26.70 202 1902224 9.04 ug/L 95 40) Butylbenzylphthalate 29.05 149 829965 9.22 ug/L 96 41) Benzo (a) antracene 30.29 228 1564090 9.80 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.92 149 1174026 9.86 ug/L 96 43) Chrysene 30.39 228 1616279 10.65 ug/L 99 45) Di-n-Octylphthalate 32.76 149 1785998 8.98 ug/L 98 46) Benzo (b) fluoranthene 33.23 252 1361141 10.43 ug/L 99

(#) = qualifier out of range (m) = manual integration REFA0312.D 5080302.M Fri Mar 15 10:08:30 2002 Page 1

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