GCMS analysis comments for sample AD29190, Dec 17 2001

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Library Search Compound Report Data File : C: \HPCHEM\ 1 \DATA\DEC10 01\29190.D Vial: 12 Acq On : 10 Dec 2001 9:28 pm Operator: 209 GALOS Sample : gc/ms scan 11/30 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Undecene, 4,5-dimethyl-, [R@ Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 35.57 1.12 ug/1 222988 Perylene-dl2 37.09 Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 2-Undecene, 4,5-dimethyl-, [R@,S@-( 182 C13H26 055170-93-9 27 2 Barbituric acid, l-butyl-5,5-diethy 240 C12H20N2O3 015517-26-7 25 3 Propanedioic acid, hexyl-, diethyl 244 C13H24O4 005398-10-7 16 4 Octane, -ethyl- 142 C10H22 015869-86-0 14 Abundance Scan 3325 (35.571 min): 29190.D (-) m/z 185.10 100.00% f 185

57 5000 70 43 112 —------ 98 143 35.20 35.40 35.60 35.80 36.00

miz-> 40 60 124 ,166 203 221 ‘11ttt12/111’11111 TTTT 80__100 120 140 160 180 200 220 240 260 280 300 240 281 297 m/z 56.95 54.77% Abundance ......... . #18485: 2-Undecene, 4,5-dimethyl-, [[email protected]@-(Z)]- 43 57 69

5000 35'20 35.40 35.60 35*80 36.00 83 98 112 140 m/z 70.10 39.21% ■ • • i ■ ■ 11 — 1 — 182 ITr T I ■ ‘ ‘ 1 ‘ ‘ I ‘ ‘ ' 1 I ‘ ‘ ‘ ' 1 1 miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #31005: Barkitaric acid 1-butyl-5,5-diethyl- 185 1I—Ar —M 35.20 35.40 35.60 35.80 36.00 5000 m/z 71.00 37.52% 212 96 114 140 155 170 ’ 197 •' I *' * ‘ I * ’ * ’ t ’ ' — TT » i » i j i i T 240 — I • ‘ 11 >b i । I i i i j » i i f । I TT r j j ' miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #32687: Propanediac acid, hexyl-, diethyl ester MPAYPTMY 57 35.20 35.40 35.60 35.80 36.00 70 m/z 55.00 34.31% 5000 83 112

42 98 — i••••i t | 199 217 ‘ !1 IT TTruu——o————t1rn——o——ICI——IIrrpoutpr T T T .8 miz—> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 35.20 35.40 35.60 35.80 36.00

29190.D GCMS1126.M Wed Dec 12 16:10:28 2001 Page 2

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