GCMS analysis comments for sample AD28669, Dec 2001

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Library Search Compound Report Data File C:\HPCHEM\l\DATA\DEC0401\28692.D Vial: 19 Acq On 5 Dec 2001 5:56 am Operator: 209 GALOS Sample gc/ms 11/24 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C: \DATABASE\NBS75K. L ********************************************************************* Peak Number 5 Butyl tetradecanoate (myristat Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 31.57 4.33 ug/1 765038 Chrysene-dl2 33.04 Hit# Of 5 Tentative MW MolForm CAS# Qual 1 Butyl tetradecanoate (myristate) 284 C18H36O2 000000-00-0 64 2 Octadecanoic acid, -methylpropyl e 340 C22H4402I 000646-13-9 50 3 Octadecanoic acid/ butyl ester 340 C22H44021 000123-95-5 45 4 1-Pentene, 2,4-dimethyl- 98 C7H14 002213-32-3 27 Abundance Scan 2889 (31.567 min): 28692.D 0 m/z 56.00 100.00% 55

5000 41 73 129 285 . T I I I I | I , /, TTTT p ■ i ■ i | > 31 20 31.40 31.60 31.80 J .J3115, 143157171 85.199 227241 27 340 TH Trr I ill TIT Jr | I TT T |Tr i I | I I II ] 1(1 i | I t i I | I I I i | । । i r | I : I > | I T t i | Pi i . ....F m/z 57.00 55.66% nfc-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #40186: Butyl tetradecanoate (myristate) 55

i p-t-r —————— 5000 229 31.20 31.40 31.60 31.80 73 211 m/z 43.05 46.91% 1 129 +1111. .... 165 1.. mm 284 . . . । < 111 । r 11 1111 111. i.. । ■. '' i" miz-> 40 60 ■ 180 200 220 240 20 340 Abundance 57 #48214: Octadecanoic acid, 2-methylpropyl ester .... IW.. 31 20 31.40 31.60 31.80 5000 m/z 41.05 43.36% 285 73 I. 97 111 129 ---------------- 185 241 207 I 340 111"1 11 mlz—> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #73570: Octadecanoic acid, butyl ester ------PPP 55 3120 31.40 31.60 31.80 m/z 55.00 31.30% 5000 285 340 73 129 267 241 I 185

m/z—> ■ ■ i" 40 — 711 .. I I ■' i' ■■ ■ i■■■ ■ i " '' i'' " I' ■ ■ ■ i " ''ir■'' i''' ■ r 1 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 —I—nmT—TTTTTTTTT 31.20 31.40 31.60 31.80

28692.D GCMS1126.M Thu Dec 06 12:39:33 2001 Page 5

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