GCMS comments for sample AD28596, Dec 2001

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2901\28596.D Vial: 40 Acq On : 30 NOV 2001 1:19 am Operator: 209 GALOS Sample : 11/23 scan Inst : GC/MS 209 Mise 2 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 5-Hexen-2-one Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 5.55 4.38 ug/1 990409 1,4-Dichlorobenzene-d4 11.70 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 5-Hexen-2-one / 98 C6H10O 000109-49-9 50 2 2-Pentanone, 3-methylene- 98 C6H10O 004359-77-7 47 3 4-Penten-2-one, 4-methyl- 98 C6H10O 003744-02-3 9 4 2-Penta: e, 5-hydroxy- 102 C5H10O2 ____ 001071-73-4 9 Abundance Scan 55 (5.552 min): 28596.D (-) m/z 42.95 100.00% 43

5000

' ' i ' ' 1 1 i • ■ ' ■ i • ■ TTT . . r. । . 1 55 83 98 207 5 20 5.40 5.60 5.80 ■ । n 111 n 11111 —+ 11 r 11 n »i । - ■ 11 > > 11111 ________________________________ '' I''" I'''11'' ’' I' ’'' l rn',T1'1111111111111111111" 111" m/z 82.90 12.14% m/z-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance #63205: 5-Hexen-2-one 43

5000 1 1 I' 1 1 I I 1 ' TTXIv 5.20 5.40 5.60 5.80 55 m/z 39.05 8.59%

mlz-> ml.TM1 15 27 83 ■ 1111111 >... । i‘i ■ ■ । 98 ■ 11 < > 11 ■ । । • 1. 11. ■ ■ ■ । ■ 1111 > 1 ।

10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 < p >. ■ । > > ■ . । ■ ■ ■ ■, ■ ■ 111111

Abundance #63190: 2-Pentanone, 3-methylene- 43 55 — fT T11 T TTIt 5 20 5.40 5.60 5.80 5000 83 m/z 54.95 5.50% 27 15

miz-> I prrr md +poopmp 10 2030405060 70 8090 100110120130140150160170180190200210 t.... ।.. i ।... 11111111 n 1111111 ii, ■ 11

Abundance #1244: 4-Penten-2-one, 4-methyl- CTTnTI 43 5 20 5.40 5.60 5.80 m/z 41.05 4.24%

5000 83

T L m .. 1.. A_. ............ 29 , 111 "111' 'T* 55 i • ■ ■■ i'" ■ i ■■ ■ 11" " i" ■ ■ i ■ ■ ■ ■ i ■■ ■ ■ i" ■ ■ i ■" ■ i" " i'"' i"1 ■ r " ’ i ” " i" ■ 111 ‘ ■ i ■11111111111 n m/z—> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 5.20 5.40 5.60 5.80

28596.D GCMS1126.M Fri NOV 30 15:30:05 2001 Page 1

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