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GCMS comments for sample AD28157, Nov 2001

Machine-extracted title · confidence 100%

Analytical commentary for sample AD28157 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

NYC-WTC_000033800–000033815

Folder label: “GCMS X 11/20/01 A 11/26/01”

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Scanned page image, NYC-WTC_000033807
OCR text

OCR status: ok · source: pdftotext

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2 601\28157.D Vial: 16 Acq On : 27 Nov 2001 1:22 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 1 1,4-Dichlorobenzene-d4 Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

11.56 0.50 ug/1 102803 1,4-Dichlorobenzene-d4 11.69

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1, 4-Dichlorobenzene-d4 150 C6C12D4 003855-82-1 50 2 Benzene-1, 2,3,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 36 3 Biphenylene 152 C12H8 000259-79-0 9 4 Vanillin 152 C8H803 000121-33-5 9 Abundance Scan 710 (11.563 min): 28157.D (-) m/z 149.90 100.00% 150

5000 115 "I 1 1 I 1 52 78 11.20 11.40 11.60 11.80 38 I, , 63 72.I . 87 -TPHH — I — .. 11 Jl l i- 4 P— m/z 151.90 72 .48% m/z—> 30 40 50 60 70 80> 90 100 10 120 130 140 150 160 Abundance #9593: 1,4-Dichlorobenzene-d4 150

5000 115 TI TT 78 11 20 11.40 11.60 11.80 52 m/z 114.95 35.39% — 87 m/z—> 30 35 11111'' । ■1 ■ ■ । 40 50 60 1' 1 1 70 80 90 100 110 —L120 130 140 150 160 Abundance #9592: Benzene-1 ,2,3,4-d4-, 5,6-dichloro- 150

1120 11.40 11.60 11.80 115 5000 52 78 m/z 78.05 18.36%

35 87 ... 1...... ■ ■ i ' 1 ' 1 i ' ' ' ' i ' ■ i1 ' ‘ ■ i ' ' I ' • • ■ l " I " " I r‘ +11 ' i ' ' 1— m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #67017: Biphenylene T" 152 11.20 11.40 11.60 11.80 m/z52.00 14.32%

5000

63 76 126 - ...... I 97 ■ ■ i'' TIWTTTTTTTTTT TT—TTtrrrrrTrrrr 1’ m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 11.20 11.40 11.60 11.80

28157.D GCMS1126.M Wed NOV 28 09:13:42 2001 Page 1

NYC-WTC_000033807

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NYC-WTC_000033807Source: NYC Law Department, mirrored locally

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Analytical commentary for sample AD28155 dated November 29, 2001, noting detection of bis(2-Ethylhexyl)phthalate and low recovery rates.

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