GCMS calibration table for TCLP analysis, Dec 2001

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Data File : C:\HPCHEM\1\DATA\DEC1901\LBB.D Vial: 27 Acq On 19 Dec 2001 4:37 pm Operator: 209 GALOS Sample : gc/msunknown 11/19 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 2 2-Hexanone Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

6.40 0.72 ug/1 307874 1,4-Dichlorobenzene-d4 11.67

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Hexanone/ 100 C6H120 000591-78-6 91 2 Oxirane,/ 2-methyl-2- (1-methylethyl) 100 C6H120 072221-03-5 86 3 2-Hexanone, 4-hydroxy-5-methyl-3-pr 172 C10H20O2 061141-74-0 83 4 2-Hexanone, 4 -hydroxy-3 -propyl- 158 C9H18O2 062338-17-4 83 ( Scan 148 (6.405 min): LBB.D (-) m/z42.95100.0 A

58 5000

37 6.00 6.20 6.40 6.60 6.80 TTTTTTTTTTTTTTTTTTTTTi m/z 58.05 ■51.64% 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 #63384: 2-Hexanone 43

5000 TTTTTTTfT Tpurrurr 6.00 6.20 6.40 16.61% 6.60 6.80 29 m/z 57.00 39 7185 100 TTUTTTTCU’TTTT TUtTTTTTTTTTTTTT TTT TTT m/z-2 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abu 43 58 6.00 6.20 6.40 6.60 6.80 5000 m/ z ....41/05........15.98%

w. 71

30 52 66 85 100 TTT UTT TTTTTTTTTTTTTTTTTTTTTT T TPUUTTTIT TTTT TTTTT TTTTTTTTTTTT TTT TTTTT TTTTTTTTTT m/z. > 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abund nce #15807: 2-Hexanone, 4-hydroxy-5-methyl-3-propyl-

. 1. 43 .. m/z 6.00 10 6.20 29% 0 6.6010.6.80 6.40

5000 - 58

72. 85 100 TTTTTTTT TTT TTTTTTCTTTTTTTTTTTTTTUUTTEItTTTTFTTT TTTTFT TTTTT1 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 6.00 6.20 6.40 6.60 6.80

LBB.D GCMS1126.M Wed Jan 02 12:10:30 2002 Page 2

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