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GCMS analysis results for sample AD26829, Dec 10 2001

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis of sample AD26829 identifying unknown compounds on December 10, 2001.

NYC-WTC_000032202–000032222

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0601\26829. D Vial: 6 Acq On 6 Dec 2001 2:44 pm Operator: GALOS Sample gc/ms unknown Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 9 2-Butanol, 3-methyl- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

7.17 5.12 ng/uL 1471640 1,4-Dichlorobenzene-d4 11.89

Hit# Of 5 entative ID MW MolForm CAS# Qual

l 2-Butanol/ 3-methyl- 88 C5H120 000598-75-4 40 2 1,2-Propanediol, 3-methoxy- 106 C4H10O3 000623-39-2 36 3 2,3 -Butanediol 90 C4H10O2 000513-85-9 33 4 N-Ethylformamide__________ __ ______ 73 C3H7NO 000627-45-2 9 Abundance Scan 254 (7.168 min): 26829.D(-) m/ z 45.10 100.00% 45

5000 61 73 —P — — - 6.80 7.00 7.20 7.40 7.60 i" " i — 11.88 11'' I'11 • | ............................................... 207 ' I ■ " ■ I ’ ■ >11 •'" I" "T" 1111111111" 111111" 11111111 "" I " " 11 m/z 43.0.0 72.20% m/z-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance #62961: 2-Butanol, 3-methyl- 45

5000 6.80 7.00 7.20 7.40 7.60

. 55 73 m/z 61.10 34.65% 27 TTTTTT 1. 1 i ■11 ■ r'" T‘TTI‘ ,..... 187........ TTTCTTT‘‘I‘T Trj<.i. ।..,, । .,,.r , ।, ,11, ,, । , , ।,, ,,,,,!.,, ,| m/z-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190 200210 Abundance #63660: 1,2-Propanediol, 3-methoxy- i 45 ..... 4........ 6.80 7.00 7.20 7.40 7.60 5000 - 75 m/ z 73.05 33.83% 31 61 15 i 88 U‘‘N"EN"TTTN‘TTUTTI‘‘T TTTTT i" " i" " i i" " i ‘ " i'"' i ■'" r " ■ i" " r'" i ‘" m/z-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190 200210 Abundance #917:2,3-Butanediol A- 45 6.80 7.00 7.20 7.40 760 m/z 44.05 15.26% 5000 -

29

.. A?1.. 1.'. L 57 75 90(T‘"IULETI"TTTTTTT‘TI"T‘i‘TT TUCTTUTUTTTTTTT Tpinpininnp-nrr I) miz- 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 6.80 7.00 7.20 7.40 7.60

26829.D NP112701.M Fri Dec 07 14:54:39 2001 Page 9

NYC-WTC_000032217

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