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GCMS comments for sample AD26532 detecting 1,1,2,2-Tetrachloroethane

Machine-extracted title · confidence 100%

Analysis report dated December 16, 2001, identifying 1,1,2,2-Tetrachloroethane at 0.80 ug/L in sample AD26532.

NYC-WTC_000031762–000031774

Folder label: “GCMS X 11/6/01 A 12/7/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\DEC0701\26532.D Vial: 8 Acq On 8 Dec 2001 12:29 am Operator: GALOS Sample gc/ms unknown 11/6 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Butanol, 3-methyl-, (S)- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

7.19 6.87 ng/uL 2151900 1,4-Dichlorobenzene-d4 11.88

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 2-Butanol, 3-methyl-, (S) - 88 C5H120 001517-66-4 40 2 2,3-Butanediol 90 C4H10O2 000513-85-9 33 3 N-Ethylformamide 73 C3H7NO 000627-45-2 9 4 2-Butanol, 3-methyl- 88 C5H120 000598-75-4 9 Abundance " Scan 256 (7.192 min): 26532.D (-) m/z 45.05 100.00% 45

5000 61 73 • P 1 1 ■ i 1 - 111111111« 36 41, | 6.80 7.00 7.20 7.40 7.60 m/z-? 5 ........ I .... 1 I I I I u11 I I I _ +56, 88 TIT | 1 I I he ! I | I I I I | 1 I t I | ! I I I | I 1 I ! | I 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 m/z 43.0,5 68.199 Abundance #852: 2-Butanol, 3-methyl-, (S) 45

5000 ----- 6.80 7.00 7.20 7.40 7.60 55 73 m/ z 73.05 35.96% 27 39 87 miz—> 5 III>|II>1| | | .III(I!IIJIIII|tII 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 mmm । ।11111111 ii 1111

Abundance #917: 2 3-Butanediol 45 11111111 — 1 ■ i ■ ‘ ■ i ■ 1 6.80 7.00 7.20 7.40 7.60 5000 m/ z 61.10 35.509 29 19 ................................. 57 — i.......................... ..................... ,.......................... 75................... 90....... 1’113 m/z—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #292: N-Ethylformamide • i 1 ■ ■ • i 1 1 i ■ 1 1 ■ i 1 • ■ 1 i ■ • 30 6.80 7.00 7.20 7.40 7.60 73 m/z 44.05 15.04 5000 44 58

mp..... H m+ 15 TO/ 11 ।"11■■■■i" ■■ i1" ■ i1 =PPr , . J Pr PPPPPPP m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 6.80 7.00 7.20 7.40 7.60

26532.D NP112701.M Thu Dec 13 11:23:12 2001 Page 2

NYC-WTC_000031771

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NYC-WTC_000031771Source: NYC Law Department, mirrored locally

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