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GCMS analysis results for sample AD26626, Dec 10 2001

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis of sample AD26626 identifying unknown compounds on December 10, 2001.

NYC-WTC_000031940–000031967

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0601\26626 .D Vial: 3 Acq On 6 Dec 2001 11:59 am Operator: GALOS Sample gc/ms unknown Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title 208 625/TCLP calibration table Library C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 8 2-Butanol, 3-methyl-, (S)- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

7.17 5.89 ng/uL 1813580 1,4-Dichlorobenzene-d4 11.89

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Butanol, -methyl-, (S)- 88 C5H120 001517-66-4 42 2 1,2 -Propanediol , 3-methoxy- 106 C4H10O3 000623-39-2 36 3 2,3-Butanediol 90 C4H10O2 000513-85-9 33 4 N-Ethylformamide 73 C3H7NO 000627-45-2 9 'Abundance Scan 254 (7.168 min): 26626.D (-) m/ z 45.10 100.00% 45

5000- 61 73

6.80 7.00 7.20 7.40 7.60 1 m/z-> 5 .... 1. 10 r • • ‘ i •" • i • TTTTTTTTT 41 +56 .... .........I" PumTTTTTp 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 88 m/z 43.0.0 67.81% 'Abundance #852: 2-Butanol, 3-methyl-,’ (S)- 45

5000- 6.80 7.00 7.20 7.40 7.60

73 m/z 61.10 34.78% 27 55

m/z-> 5 I' *' ‘ i 10 M I yrm TTTTTTTTTTT 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 87 1 ‘'11 r Abundance #63660: 1,2-Propanediol, 3-methoxy- 45 ........... /......................... 6.80 700 7.20 .4( 7.60 5000 75 m/ z 73.05 33.90% 31 61 15 ‘ I 88 । * ।" ।" 1111 •»। I ‘"'I i’•*‘i‘ * r • • • i • •' • r • • • i • *" i •" • i • •" i I'1'11 P m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #917: 2,3-Butanediol .............. ................. 45 6.80 7.00 7.20 7.40 7.60 m/z 44.00 13.56% 5000

29 | m/z--: 5 19 h 4 mH । 57 | 75 90 HTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTT 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 r 6.80 7.00 7.20 7.40 7.60 |

26626.D NP112701.M Fri Dec 07 14:50:12 2001 Page 8

NYC-WTC_000031953

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NYC-WTC_000031953Source: NYC Law Department, mirrored locally

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