GCMS calibration data for TCLP analysis dated December 7, 2001

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Library Search Compound Report Data File C: \HPCHEM\ 1 \DATA\DEC0 7 01 \LB. D Vial: 2 Acq On 7 Dec 2001 7:01 pm Operator: GALOS Sample gc/ms unknown 11/6 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 5 Propanoic acid, 2-methyl-, anh Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 6.10 2.47 ng/uL 765751 1,4-Dichlorobenzene-d4 11.88 Hit# of 5 Tentative ID MW MolForm CAS# Qual l Propanoic id, 2-methyl-, anhydrid 158 C8H14O3 000097-72-3 42 2 2 -Furanol, tetrahydro-2-methyl- 102 C5H10O2 007326-46-7 39 3 2-Hepten-3-ol, 4,5-dimethyl- 142 C9H180 055956-37-1 38 4 Azetidine, 2-methyl - 71 C4H9N 019812-49-8 9 Abundance 7 Scan 137 (6.096 mln): LB.D (-) m/z 71.05 100.00% 71

5000 43

i ■P'— i। 55 5.80 6.00 6.20 6.40

miz-> = 10 20 ... 4 30 40 —4601 —............... ........ .................................. 50 70) 80 90 100 110 120 130 m/ Z 43.05 43.84% Abundance #11901: Propanoic acid, 2-methyl-, anhydride 71

43 5000 15.80 6.00 6.20 6.40 m/z 41.10 24.76% 27 — 3740+ +55 ..... ‘ I ' 1 ' ‘ I ‘ ‘ I ' ' ' • I ' 1 1 1 I ' 1 1 1 I '

A miz-> 10 20 30 50 60 70 80 90 100 110 120 130 Abundance #63475:2-FuranoI, tetrahydro-2-methyl- 71

5.80 6.00 6.20 1 “6.40 5000 43 m/z 42.10» 19.93%

Jl 49 55 61 , 84 '1 i ■ ■j । II । k .. fl i i > । i i i i । i i i । । । । i । । i it । |'r ■ i i । i miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #8051:2-Hepten-3-ol, 4,5-dimethyl- —TMTT 7|1 5.80 6.00 8.20 6.40 m/z 39.00 11.72% 5000 43

27 15 55 81 100 109 124 m/z—> II । ■ ■ i ■ ■ ' • i ■ ■ ’ ■ i ■ ■ ■ ■ i ■' ' TI 11111 1 10 20 30 40 50 60 "7 TIPOIguur T T ■ ' * I ‘ ‘ ‘ ' I * 1 * ' i ‘ 80 90 100 110 120 130 A—A,AA 5.80 6.00 6.20 6.40

LB.D NP112701.M Thu Dec 13 11:28:30 2001 Page 5

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