Volatile organic compounds results, Mar 12 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02MAR12\0312R5A.D Vial: 5 Acq On : 12 Mar 2002 11:49 am Operator: 201-wb Sample : ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 12 13:24 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 12 13:23:20 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. QIon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.07 114 1874210 5.00 ug/L -0.10 24) CHLOROBENZENE-D5 21.73 117 1531412 5.00 ug/L -0.10 52) 1,4-DICHLOROBENZENE-D4 26.90 152 772963 5.00 ug/L -0.10 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.30 65 744078 6.14 ug/L -0.10 Spiked Amount 5.000 Recovery = 122.80% 3) 4-BROMOFLUOROBENZENE 24.31 174 593354 3.91 ug/L -0.10 Spiked Amount 5.000 Recovery = 78.20% 25) TOLUENE-D8 18.42 98 2236426 6.06 ug/L -0.10 Spiked Amount 5.000 Recovery = 121.20% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 252444 5.13 ug/L 97 5) CHLOROMETHANE 5.49 50 264623 4.87 ug/L 98 6) VINYL CHLORIDE 5.59 62 215710 6.01 ug/L 95 7) BROMOMETHANE 6.56 94 157262 4.84 ug/L 94 8) CHLOROETHANE 6.69 64 156107 5.23 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.26 101 320767 4.67 ug/L 98 12) ACETONE 8.22 43 63368 5.54 ug/L 99 13) 1,1-DICHLOROETHENE 8.58 61 417759 5.12 ug/L 99 14) METHYLENE CHLORIDE 9.59 49 391379 4.07 ug/L 96 15) METHYL TERT BUTYL ETHER 9.89 73 392608 3.56 ug/L 98 16) TRANS-1,2-DICHLOROETHENE 10.25 61 429161 3.88 ug/L 97 17) 1,1-DICHLOROETHANE 11.14 63 520093 3.81 ug/L 99 18) 2-BUTANONE (MEK) 11.97 43 55236 2.69 ug/L 92 19) 2,2-DICHLOROPROPANE 12.36 77 405431 4.02 ug/L 97 20) CIS-1,2-DICHLOROETHENE 12.45 96 317046 3.77 ug/L 99 21) CHLOROFORM 12.79 83 571275 3.98 ug/L 99 22) BROMOCHLOROMETHANE 13.16 49 233412 3.30 ug/L 92 23) 1,2-DICHLOROETHANE 14.51 62 393261 4.34 ug/L 98 26) 1,1,1-TRICHLOROETHANE 13.67 97 424049 5.18 ug/L 98 27) 1,1-DICHLOROPROPENE 14.00 75 407989 5.08 ug/L 97 28) CARBON TETRACHLORIDE 14.25 117 362111 5.27 ug/L 97 29) BENZENE 14.59 78 1053154 4.64 ug/L 97 30) TRICHLOROETHENE 15.87 95 325274 4.87 ug/L 98 31) 1,2-DICHLOROPROPANE 16.23 63 272975 4.14 ug/L 97 32) DIBROMOMETHANE 16.91 174 142182 4.11 ug/L 97 33) BROMODICHLOROMETHANE 16.74 83 386870 4.68 ug/L 100 34) 2-CHLOROETHYL VINYL ETHER 17.23 63 81647 3.91 ug/L 98 35) METHYL ISO-BUTYL KETONE 17.32 58 36313 3.09 ug/L 98 3 6) CIS-1,3-DICHLOROPROPENE 17.84 75 374794 4.17 ug/L 98 37) TOLUENE 18.59 91 1146078 4.59 ug/L •100 38) TRANS-1,3-DICHLOROPROPENE 18.87 75 292239 4.54 ug/L 97 39) 1,1,2-TRICHLOROETHANE 19.26 97 182467 4.26 ug/L 98 40) TETRACHLOROETHENE 20.04 166 316057 4.41 ug/L 98 41) 1,3-DICHLOROPROPANE 19.78 76 325436 4.14 ug/L 99 42) DIBROMOCHLOROMETHANE 20.48 129 223979 4.35 ug/L 96 43) 1,2-DIBROMOETHANE 20.93 107 159290 3.65 ug/L 100 44) CHLOROBENZENE 21.81 112 683215 3.99 ug/L 98 45) 1,1,1,2-TETRACHLOROETHANE 21.86 131 229649 4.05 ug/L 98 46) 2-HEXANONE 19.15 ' 43 70648 2.36 ug/L 89 47) ETHYLBENZENE 21.84 91 1223795 4.32 ug/L 100 48) P & M-XYLENE 22.00 106 838006 8.21 ug/L 93 (#) = qualifier out of range (m) = manual integration 0312R5A.D HP022702.M Tue Mar 12 13:24:41 2002 Page 1

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