Volatile organic compounds results, Mar 10 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\O2MAR10\5231.D Vial: 4 Acq On : 10 Mar 2002 4:56 pm Operator: 201-wb Sample : nyc Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Library : C:\DATABASE\NBS75K.L

Peak Number 2 1-(Propenylthio)prop-l-ene Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

15.75 0.03 ug/L 23068 1,4-DIFLUOROBENZENE 15.09

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-(Propenylthio)prop-l-ene 114 C6H10S 000000-00-0 3 2 2,4-Imidazolidinedione, 3-methyl- 114 C4H6N2O2! 006843-45-4 3 3 3-Cyclobutene-l,2-dione, 3,4-dihydr 114 C4H204 002892-51-5 2 4 2,4,5-Trioxoimidazolidine 114 C3H2N203!000120-89-8 2 Abundance Scan 692 (15.749 min): 5231 .D (-) m/z 114.15 100.00% 1 4

5000 1... ........... 63 88 15.40 15.60 15.80 16.00 50 | — m/z 88.00 27.11% m/z-> ‘I 1'* ’I ’ * ‘ ‘ I ‘ ’ I ’' ‘ ‘ I’‘‘I‘' 11 10 20 30 40 50 60 70 80 90 100 110 120 * ■ i * * A Abundance #2940:1-(Propenylthio)prop-1-ene 1 4 41 99

5000 15.40 15.60 15.80 16.00 m/z 63.05 26.81%

m/z--> ‘ ‘ I ‘ ‘‘ I ‘‘ ‘ I ‘ 10 20 59.7 ‘ ‘ 11‘11 I'‘‘ I ‘‘ ‘ 1* l l I > * > * I I I 30 40 50 60 70 80 90 100 110 120 I"“I i ■ ■

Abundance #64088:2,4-lmidazolidinedione, 3-methyl- 1 4 *1***1144 ■ i ■ ■ ■ ■ i • ■ ‘ • i •

15.40 15.60 15.80 16.00 58 m/z 50.05 18.92% 5000

86 42 71 i ■ • • ■ i ■ ■ ‘11 ■' ' • i ' ‘■ i ' ■ ■ ■ i' ‘ ' i ‘ ‘ i ' • 111 •111 * ■1 * i1 ■ ■ i''

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #2826:3-Cyclobutene-1,2-dbne, 3,4-dihydroxy- 29 ■ j ■ ■ ‘ ' i ■ ' ' f i ■ 'I 1 " ' 1 1 58 15.40 15.60 15.80 16.00

5000 114

86 17 40 -PH - 68 i ■ ■ ■ ■ i ■ ■'' i'' ■ i • ■ ■ ■ i ■ ■ ■ ■ i' ■ • i'1 n/z—> 10 20 30 40 50 60 70 80 90 100 110 120

5231.D HP022702.M Mon Mar 11 11:21:04 2002 Page 2

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