Volatile organic compounds blank results, Mar 8 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\l\DATA\02mar08\0308R5A.D Vial: 6 Acq On 8 Mar 2002 2:45 pm Operator: 201-wb Sample ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 8 15:23 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.05 114 1487581 5.00 ug/L -0.12 24) CHLOROBENZENE-D5 21.69 117 1426221 5.00 ug/L -0.14 52) 1,4-DICHLOROBENZENE-D4 26.88 152 707601 5.00 ug/L -0.12

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.28 65 570680 5.93 ug/L -0.12 Spiked Amount 5.000 Recovery = 118.60% 3) 4-BROMOFLUOROBENZENE 24.28 174 534839 4.44 ug/L -0.14 Spiked Amount 5.000 Recovery = 88.80% 25) TOLUENE-D8 18.39 98 1838473 5.35 ug/L -0.14 Spiked Amount 5.000 Recovery = 107.00%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.83 85 169863 4.39 ug/L 97 5) CHLOROMETHANE 5.45 50 213489 4.95 ug/L 98 6) VINYL CHLORIDE 5.57 62 163323 6.46 ug/L 98 7) BROMOMETHANE 6.54 94 151379 5.72 ug/L 90 8) CHLOROETHANE 6.68 64 138344 5.79 ug/L 96 9) TRICHLOROFLUOROMETHANE 7.23 101 261864 4.80 ug/L 99 12) ACETONE 8.21 43 55035 7.23 ug/L 96 13) 1,1-DICHLOROETHENE 8.56 61 290878 4.49 ug/L 98 14) METHYLENE CHLORIDE 9.57 49 405076 5.31 ug/L 99 15) METHYL TERT BUTYL ETHER 9.88 73 354623 4.05 ug/L 97 16) TRANS-1,2-DICHLOROETHENE 10.23 61 361549 4.12 ug/L 100 17) 1,1-DICHLOROETHANE 11.12 63 457438 4.22 ug/L 98 18) 2-BUTANONE (MEK) 11.95 43 54887 3.37 ug/L{ 91 19) 2,2-DICHLOROPROPANE 12.33 77 351972 4.40 ug/L 96 20) CIS-1,2-DICHLOROETHENE 12.43 96 285309 4.27 ug/L 97 21) CHLOROFORM 12.77 83 507761 4.46 ug/L 97 22) BROMOCHLOROMETHANE 13.14 49 219532 3.91 ug/L 97 23) 1,2-DICHLOROETHANE 14.49 62 347796 4.83 ug/L 100 26) 1,1,1-TRICHLOROETHANE 13.65 97 362788 4.76 ug/L 99 27) 1,1-DICHLOROPROPENE 13.98 75 362887 4.85 ug/L 97 28) CARBON TETRACHLORIDE 14.23 117 296393 4.63 ug/L 99 29) BENZENE 14.57 78 964624 4.56 ug/L 98 30) TRICHLOROETHENE 15.85 95 298194 4.79 ug/L 99 31) 1,2-DICHLOROPROPANE 16.21 63 267705 4.36 ug/L 99 32) DIBROMOMETHANE 16.87 174 127737 3.97 ug/L 86 33) BROMODICHLOROMETHANE 16.72 83 359205 4.66 ug/L 96 34) 2-CHLOROETHYL VINYL ETHER 17.21 63 84838 4.36 ug/L 96 35) METHYL ISO-BUTYL KETONE 17.28 58 40652 3.72 ug/L 98 36) CIS-1,3-DICHLOROPROPENE 17.81 75 366169 4.37 ug/L 97 37) TOLUENE 18.58 91 1086879 4.68 ug/L 97 38) TRANS-1,3-DICHLOROPROPENE 18.85 75 283849 4.74 ug/L 98 39) 1,1,2-TRICHLOROETHANE 19.24 97 178460 4.47 ug/L 96 40) TETRACHLOROETHENE 20.02 166 286237 4.29 ug/L 98 41) 1,3-DICHLOROPROPANE 19.77 76 324008 4.43 ug/L 98 42) DIBROMOCHLOROMETHANE 20.45 129 206341 4.30 ug/L 99 43) 1,2-DIBROMOETHANE 20.91 107 173161 4.26 ug/L 99 44) CHLOROBENZENE 21.78 112 722415 4.53 ug/L 96 45) 1,1,1,2-TETRACHLOROETHANE 21.83 131 241424 4.57 ug/L 97 46) 2-HEXANONE 19.14 43 78532 2.82 ug/L 99 47) ETHYLBENZENE 21.83 91 1297386 4.92 ug/L 99 48) P & M-XYLENE 21.98 106 898045 9.45 ug/L 98 (#) = qualifier out of range (m) = manual integration 0308R5A.D HP022702.M Fri Mar 08 15:24:02 2002 Page 1

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