Volatile organic compounds results, Mar 7 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File C:\HPCHEM\1\DATA\02mar07\03 07C10A.D Vial: 2 Acq On 7 Mar 2002 5:14 pm Operator: 201-wb Sample cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 7 17:52 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.07 114 1452274 5.00 ug/L -0.10 24) CHLOROBENZENE-D5 21.72 117 1416317 5.00 ug/L -0.10 52) 1,4-DICHLOROBENZENE-D4 26.90 152 694075 5.00 ug/L -0.10 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.30 65 579106 6.17 ug/L -0.10 Spiked Amount 5.000 Recovery = 123.40% 3) 4-BROMOFLUOROBENZENE 24.31 174 537834 4.57 ug/L -0.10 Spiked Amount 5.000 Recovery = 91.40% 25) TOLUENE-D8 18.42 98 1803544 5.28 ug/L -0.10 Spiked Amount 5.000 Recovery = 105.60% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.83 85 481952 11.69 ug/L 98 5) CHLOROMETHANE 5.49 50 415052 9.59 ug/L 98 6) VINYL CHLORIDE 5.57 62 318626 13.92 ug/L 96 7) BROMOMETHANE 6.56 94 343088 12.39 ug/L 93 8) CHLOROETHANE 6.69 64 335580 13.83 ug/L 96 9) TRICHLOROFLUOROMETHANE 7.25 101 629219 11.81 ug/L 100 12) ACETONE 8.22 43 114309 15.38 ug/L 99 13) 1,1-DICHLOROETHENE 8.58 61 632276 10.00 ug/L 95 14) METHYLENE CHLORIDE 9.59 49 843393 11.31 ug/L 99 15) METHYL TERT BUTYL ETHER 9.89 73 876237 10.26 ug/L 99 16) TRANS-1,2-DICHLOROETHENE 10.25 61 853286 9.95 ug/L 99 17) 1,1-DICHLOROETHANE 11.13 63 1054416 9.96 ug/L 98 18) 2-BUTANONE (MEK) 11.97 43 130893 8.23 ug/L 93 19) 2,2-DICHLOROPROPANE 12.36 77 766070 9.81 ug/L 96 20) CIS-1,2-DICHLOROETHENE 12.45 96 634660 9.74 ug/L 95 21) CHLOROFORM 12.79 83 1139678 10.25 ug/L 99 22) BROMOCHLOROMETHANE 13.16 49 513943 9.38 ug/L 99 23) 1,2-DICHLOROETHANE 14.51 62 807024 11.48 ug/L 100 26) 1,1,1-TRICHLOROETHANE 13.67 97 815065 10.76 ug/L 98 27) 1,1-DICHLOROPROPENE 13.99 75 849837 11.45 ug/L 98 28) CARBON TETRACHLORIDE ' 14.27 117 691708 10.88 ug/L 99 29) BENZENE 14.61 78 2231134 10.62 ug/L 99 30) TRICHLOROETHENE 15.87 95 677028 10.96 ug/L 97 31) 1,2-DICHLOROPROPANE 16.22 63 638411 10.48 ug/L 100 32) DIBROMOMETHANE 16.91 174 317600 9.93 ug/L 97 33) - BROMODICHLOROMETHANE 16.75 83 861991 11.27 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.23 63 228021 11.79 ug/L 98 35) METHYL ISO-BUTYL KETONE 17.31 58 113602 10.46 ug/L 92 36) CIS-1,3-DICHLOROPROPENE 17.84 75 911211 10.96 ug/L 98 37) TOLUENE 18.59 91 2511595 10.88 ug/L 100 38) TRANS-1,3-DICHLOROPROPENE 18.88 75 713229 11.99 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.26 97 440749 11.11 ug/L 98 40) TETRACHLOROETHENE 20.04 166 668115 10.08 ug/L 99 41) 1,3-DICHLOROPROPANE 19.78 76 809462 11.13 ug/L 99 42) DIBROMOCHLOROMETHANE 20.48 129 515919 10.84 ug/L 98 43) 1,2-DIBROMOETHANE 20.92 107 444760 11.01 ug/L 100 44) CHLOROBENZENE 21.81 112 1677070 10.60 ug/L 96 45) 1,1,1,2-TETRACHLOROETHANE 21.86 131 565842 10.78 ug/L 99 46) 2-HEXANONE 19.15 43 202214 7.31 ug/L 95 47) ETHYLBENZENE 21.84 91 3011466 11.49 ug/L 99 48) P & M-XYLENE 22.00 106 2046097 21.67 ug/L 95 (#) = qualifier out of range (m) = manual integration 0307C10A.D HP022702.M Thu Mar 07 17:53:13 2002 Page 1

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