VOC analysis results, sample AE03384, Feb 17 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02FEB17\0217R5.D Vial: 3 Acq On : 17 Feb 2002 1:39 pm Operator: 201-wb Sample : reference 5 Inst : GC/MS Ins Mise : February 15, 2002 Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 18 16:26 2002 Quant Results File: HP021702.RES Quant Method : C:\HPCHEM\1\METHODS\HP021702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Fri Feb 15 09:42:18 2002 Response via : Initial Calibration DataAcq Meth : HP021302

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.15 114 2064628 5.00 ug/L 0.03 24) CHLOROBENZENE-D5 21.81 117 1945288 5.00 ug/L 0.05 52) 1,4-DICHLOROBENZENE-D4 26.98 152 868658 5.00 ug/L 0.03 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.38 65 723897 4.61 ug/L 0.03 Spiked Amount 5.000 Recovery = 92.20% 3) 4-BROMOFLUOROBENZENE 24.39 174 641156 4.13 ug/L 0.03 Spiked Amount 5.000 Recovery = 82.60% 25) TOLUENE-D8 18.51 98 2521269 5.23 ug/L 0.03 Spiked Amount 5.000 Recovery = 104.60% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.89 85 295996 4.07 ug/L 97 5) CHLOROMETHANE 5.54 50 250207 3.97 ug/L 98 6) VINYL CHLORIDE 5.64 62 163588 6.31 ug/L 95 7) BROMOMETHANE 6.63 94 123853 3.68 ug/L 97 8) CHLOROETHANE 6.76 64 118802 3.50 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.32 101 231438 3.55 ug/L 100 12) ACETONE 8.31 43 75540 5.32 ug/L 90 13) 1,1-DICHLOROETHENE 8.65 61 410604 4.14 ug/L 97 14) METHYLENE CHLORIDE 9.66 49 628942 5.27 ug/L 98 15) METHYL TERT BUTYL ETHER 9.96 73 505949 3.84 ug/L 97 16) TRANS-1,2-DICHLOROETHENE 10.33 61 544236 4.29 ug/L 99 17) 1,1-DICHLOROETHANE 11.21 63 691948 4.61 ug/L 98 18) 2-BUTANONE (MEK) 12.05 43 143345 4.36 ug/L 98 19) 2,2-DICHLOROPROPANE 12.43 77 516280 4.29 ug/L 96 20) CIS-1,2-DICHLOROETHENE 12.52 96 418978 4.89 ug/L 97 21) CHLOROFORM 12.87 83 723653 4.80 ug/L 99 22) BROMOCHLOROMETHANE 13.25 49 346837 4.84 ug/L 99 23) 1,2-DICHLOROETHANE 14.59 62 466879 4.60 ug/L 96 26) 1,1,1-TRICHLOROETHANE 13.75 97 514407 4.74 ug/L 98 27) 1,1-DICHLOROPROPENE 14.09 75 560310 5.18 ug/L 98 28) CARBON TETRACHLORIDE 14.35 117 ' 415093 4.71 ug/L 99 29) BENZENE 14.68 78 1501531 5.34 ug/L 99 30) TRICHLOROETHENE 15.96 95 443576 5.28 ug/L 95 31) 1,2-DICHLOROPROPANE 16.31 63 446160 5.62 ug/L 99 32) DIBROMOMETHANE 16.99 174 188287 4.99 ug/L 99 33) BROMODICHLOROMETHANE 16.84 83 534284 5.26 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.31 63 125159 4.26 ug/L 94 35) METHYL ISO-BUTYL KETONE 17.39 58 69962 4.81 ug/L 98 36) CIS-1,3-DICHLOROPROPENE 17.91 75 591318 5.28 ug/L 99 37) TOLUENE 18.68 91 1668355 5.68 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.96 75 447288 5.45 ug/L • 99 39) 1,1,2-TRICHLOROETHANE 19.34 97 267265 5.62 ug/L 96 40) TETRACHLOROETHENE 20.12 166 431406 5.40 ug/L 93 41) 1,3-DICHLOROPROPANE 19.88 76 505355 5.42 ug/L 99 42) DIBROMOCHLOROMETHANE 20.56 129 297373 5.19 ug/L 98 43) 1,2-DIBROMOETHANE 21.01 107 265464 5.15 ug/L 98 44) CHLOROBENZENE 21.90 112 1112040 5.93 ug/L 96 45) 1,1,1,2-TETRACHLOROETHANE 21.95 131 350822 5.59 ug/L 96 46) 2-HEXANONE 19.24 43 168240 5.76 ug/L 97 47) ETHYLBENZENE 21.93 91 1998149 5.90 ug/L 97 48) P & M-XYLENE 22.09 106 1380472 11.95 ug/L 93 (#) = qualifier out of range (m) = manual integration 0217R5.D HP021702.M Mon Feb 18 16:26:53 2002 Page 1

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