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GCMS analysis results, sample AD30315, Jan 2002

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Gas chromatography-mass spectrometry analysis report for sample AD30315, completed January 9, 2002, showing unknown compounds data.

NYC-WTC_000019163–000019173

Folder label: “GCMS X 12/13/01 A 12/22/01 AND 12/27/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\DEC2101\30315.D Vial: 6 Acq On : 22 Dec 2001 11:44 am Operator: 209 GALOS Sample : gc/ms scan 12/13a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Acenaphthene-diO Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

20.56 20.97 ug/1 6068400 Phenanthrene-dl0 24.97

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acenaphthene-d10 164 C12D10 015067-26-2 72 2 Thiophene, 2-bromo- 162 C4H3BrS 001003-09-4 38 3 2H-1,5-Benzodioxepin, 3,4-dihydro-3 162 C10H10O21 019560-64-6 17 4 2-Benzothiazolamine, N-methyl- 164 C8H8N2S 016954-69-1 10 Abundance Scan 1690 (20.556 min): 30315.D(-) m/z " 100.00% (4

5000 80 FEBBBEgTTTTTTTT

miz-> 30 42 111'11111 ■1 40 —5047ul 54

60 70 80 66 90 100 108115122 132 146 156 1 +|rt i r pt l *iy i l I 1 I III I [ +ttn I I I I I I I i 1'1 I1 90 100 110 120 130 140 150 160 170 20.20 20.40 20.60 20.80 m/z 162.05 94.76% Abundance #13561: Acenaphthene-d10 162

i 5000 20.20 20.40 20.60 20.80 ' ' 1 ' 80 m/z 160.05 40.89% 66 mDPPPHI 132 . ■ ■ i' ■1 ■ i ■ • ■ ■ i •' ■ ■ i ■'' ■ i1 ■' ■ i ■' ■11 • ■11 l_____ *41’4 m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #12743. Thiophene, 2-bromo- 162 __________ V __________ k | > I ! I J-1 TT I । i I > i । i i i i । jl 20.20 20.40 20.60 20.80 5000 83 m/z 80.05 26.85% 45 38 58 i i; 117 . • i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ • i ■ ■ ■11■ ■ ■ ■i'■■■i■'■'i11'■i■■■■i1■■■i■■■■i■■■■ i " • ■ 1111' 11' miz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #12916:2H-1,5-Benzodioxepin, 3,4-dihydro-3-methylene- 1 । • ■ • ■ । 1 1 1 1 IT" । । । i i । । । । 162 20.20 20.40 20.60 20.80 m/z 163.15 20.78% 5000 52 80 92 66 Tytttrgv - hmmmmmmm J111113 ____110 121 134 147 ' । ■ ■ ■111' ■ ■ । ■ ■ • ■ । • •' * ।' miz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 20,20 20.40 20.60 20.80

30315.D GCMS1126.M Wed Jan 02 10:19:19 2002 Page 2

NYC-WTC_000019171

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