GCMS analysis results, sample AD30936, January 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C: \HPCHEM\ 1 \DATA\ JAN2 502\30936A.D Vial: 3 Acq On : 25 Jan 2002 11:09 am Operator: 209 GALOS Sanpl e : REINJECT Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 4 Cyclopentasiloxane, decamethyl Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 14.13 0.88 ug/1 327376 Naphthalene-d8 15.08 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Cyclopentasiloxane, camethyl- 370 C10H30O5S15 000541-02-6 83 2 N-(Trifluoracetyl)- ,O',0"-tris(tri 495 C20H36F3N04Si3 000000-00-0 43 3 Benzoic acid, 2-[ (trimethylsilyl)ox 282 C13H22O3Si2 003789-85-3 43 4 Benzoic acid, 2,5-bis(trimethylsilo 370 C16H3004Si3 003618-20-0 43 ^Abundance in 990 (14.132 min): 30936A.D (-) m/ Z 73.00 1 00.00% 73 | 5000 267 355 Bnmmmm,TTp 45 108 133154 1?3 223 , 13.80 14.00 14.20 14.40 - ITT4**Ir 323 i»A ■ m/z 267.0,0 33.42% m/z-> 50 100 150 200 250 300 350 400 450 500 Abundance #51266: Cyclopentasiloxane, decamethyl- 73 355 1 267 5000 I 13.80 14.00 14.20 14.40 ‘ ‘ ‘ m/z 355.05 22.63% , I, 207 , I 323 g*,’ It k t , , i I I ■ ■ i ' • ■ ‘ i ■ ■‘ ■ i • ■ • • i ' ■ 1__ j__d । A__ P__ —i miz-> 50 100 150 200 250 300 350 400 450 500 Abundance #58807: N-(Tnfluoracetyl>O>O'.O*-tris(trimethylsilyl)epin 73 355 .............. M................ **I***I*-+I*---1-*$*I 13.80 14.00 14.20 14.40 5000 m/z 268.0.0 9.46% 45 140 184 281 | 480 i । > T013B9/—9—n——m—ma——————— m/z-? 50 100 150 200 250 300 350 400 450 500 Abundance #72298: Benzoic acid, 2-[(trimethylsilyl)oxy]-, trimethylsi 1 1 I ■ • • ■ i ■ ■ 1 ■ i ■ ‘ • i 1 • ■ 1 i 73l 267 13.80 14.00 14.20 14.40 m/z 74.00 8.52% 5000

135 405 I miz-> 47 118* 1** 4L4rani 150 200 233250 .. 300 350 400 450 ‘ 500 ■ ■ i 1 • ■ 1 i ■ • •■ i r' 1 1 f 1 1 1 1 1 50 100 13.80 14.00 14.20 14.40

30936A.D GCMS1126.M Fri Jan 25 12:23:55 2002 Page 4

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