Pesticide analysis results, sample AE11755, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\051302\LBB0513.D Vial: 12 • Acq On : 13 May 2002 8:50 pm Operator: Bohlk / Inst 213 Sample : LB 5/13/02 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l\5973N\050802.M (RTE Integrator) Title : Quantitation For Method 525.2 Library : C:\DATABASE\WILEY7N.L

Peak Number 4 [2.2](2,6)pyrazinophane Concentration Rank 1

R.T.

26.65

Hit# of EstConc

5.27 ug/L

5 Area

3965870 . Relative to ISTD

p-Terphenyl d-14 R.T.

27.42 a d - /o rewe

Tentative ID MW Mol Form CAS# Qual 1 [2.2](2,6)pyrazinophane 212 C12H12N4 123624-86-2 64 2 [1,1'-Biphenyl]-4,4'-diamine, 3,... 212 C14H16N2 000119-93-7 59 3 [1,1'-Biphenyl]-4,41-diamine, 3,... 212 C14H16N2 000119-93-7 59 4 Benzenamine, 2-methoxy-N- (4-pyri.. . 212 C13H12N2O 041855-68-9 59 Abundance Scan 1717 (26.650 mln): LBB0513.D (-) m/z 212.20 100.00% 2 12

5000

106 ---------------- 92 t 26.40 26.60 26.80 27.00 52 66 78 1 . 124136 156168 180 194 ... m/z 106.10 22.37% Ott —IPITTmmt" m/z-> 20 40 60 80 100 120 140 160 180 200 220 Abundance #132924: [2.2](2,6)pyrazinophane 2 2

5000 _ . 26.40 26.60 26.80 27.00 185 m/z 213.20 18.25% 158

m/z-> Or ................... 114.1171, 20 ' 40 ' 60'“ 80 100 120 140 160 180 197

200 220 Abundance #133756: [1,T-Biphenyl]-4,4'-diamine, 3,3‘dimethyl- $$ B... 212

*Pmmm 26.40 26.60 26.80 27.00 5000 m/z 211.20 17.03%

106 28 51 65 77 91 . ] 118130 152 168180 196 m/z-> OVr *1mPPT-mmmm 20 40 60 80 100 120 140 160 180 200 220 Abundance #133759: [1,1‘-Biphenyl]-4,4‘-diamine, 3,3‘-dimethyl- $$ B... 212 । n । | 11 । > I 1 ' 26.40 26.60 26.80 27.00 m/z 208.20 16.49%

5000

28 106 51 65 77 91 , j 118130 152 168180 1° 20 0‘i 1 1 । । । '|" 1 1’1 । Ti ■■ r’ rt iV-pTh ■ T 11"r । "th i"|"t 1 <4'| i r m/z—> 20 40 60 80 100 120 140 160 180 200 220 26.40 26.60 26.80 27.00

BB0513.D 050802.M Tue May 14 11:03:09 2002 Page 6

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