GCMS quantitation report, sample LB, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\061102\LB.D Vial: 4 Acq On : 11 Jun 2002 12:19 pm Operator: Sample : gc/ms scan 6/11 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 l-Buten-3-yne, 1-chloro-, (E) - Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T.

3.89 5.04 ug/L 3766210 1,4-dichlorobenzene-d4 9.89

Hit# of /5 Tentative ID MW MolForm CAS# Qual

1 1-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-91-8 9 2 1-Buten-3-yne, 1-chloro-, (Z)- 86 C4H3C1 020374-90-7 9 3 Thiophene 84 C4H4S 000110-02-1 7 4 Thiophene____ 84 C4H4S 000110-02-1 7 Abundance/ Scan 138 (3.890 min): LB.D (-137) (-) m/z 84.00 100.00% 51 84

5000

37 41 57 88 3.60 3.80 4.00 4.20 01 mmmmmmmmmHHHHp 1111" p 1 HHpm m/z 86.00 91.60% m/z-> 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12408: 1-Buten-3-yne, 1-chloro-, (E)- 51 ' 85

5000 3.60 3.80 4.00 4.20 m/z §1.05 90.34% . 60 0- |“U| .... ।.... ।.. 111 ■ 11111.111.... ।.... ।. ■. 1111111111111111| ■ I | Hmmp 1uI1n■[■1“| miz-> 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #111070:1-Buten-3-yne, 1-chloro-, (Z)- 51 86

3.60 3.80 4.00 4.20 5000 m/z 48.10 16.70%

0- i, > । >,, > । >,, > । >। < > > > । >, > > ।> 11111111111111111111 60 I>(।nwJu 111 >n> । >>> • ।. i>> । > > > > [ Hmmp MMpw /MMhar, miz-> 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33732: Thiophene 84 3.60 3.80 4.00 4.20 m/z 57.00 15.97% 58 45 5000 39 AJ Wurlk NN

50 ।

m/z-> 0 1 12 26 32 TTTHTT++++++ ■ti i I | 1> । । । i I 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 +44.F4.4.8Q41l48%,. TTp-rT

3.60 3.80 4.00 4.20

LB.D 060302.M Tue Jun 11 15:54:53 2002 Page 7

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