GCMS sample AE12764 results, June 10 2002

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Data File C:\MSDCHEM\l\DATA\060702\12764.D Vial: 4 Acq On 7 Jun 2002 11:02 am Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 15 Borane, trifluoro- Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T. 5.46 0.40 ug/L 236789 1,4-dichlorobenzene-d4 9.89 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Borane, trifluoro- 68 BF3 007637-07-2 2/ 2 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7/2 3 Ethyl Chloride 64 C2H5C1 000075-00-3 2 4 Formamide, N-(cyanomethyl)- 84 C3H4N2O 005018-27-9 2 Abundance Scan 405 (5.459 min): 12764.D (-403) (-) m/z 84.00 200.00% 84 49

5000

40 5.20 5.40 5.60 5.80 0- i' 1 ■ ■ i1 ■ ■ ■ i 1 ' ■ ■ i ■ m/z 49.10 70.23% niz-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12321: Borane, trifluoro- 49

5000 5.20 5.40 5.60 5.80 m/z "... 48.05 18.89% 11 19 30 38 68 0- ■ ■ '1 11 ■ ■' i ■ ■ ■ ■ 11 ■ ■ ■ i ■ • -Tp—p m/z—> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #1099: Boron trifluoride etherate 31

59 ' ‘ 5.20 5.40' 5.60 5.80 5000 45 m/z 40.05 14.41% 74

0- — 15 +2 +3944——— —Hr 66 81 93 127 ■ ■ i ■ ■ ■ • i ■ ■ ■ ■ i • •1 ■ i ■ ■ ■ ■ i ■ • ■ ■ i ■ • MaphjMk/lAMvusAmMas niz-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #107943: Ethyl Chloride 23 5.20 5.40 5.60 5.80 m/z 41.05 3.34% 5000

49 64 "WyMtyataky 15 35 0-m I 4L, jt tr■ lpr ■ i 14, mll ■ i ■ ‘1 ■ i ■ ■ ■ • i ■1 ■ ■ i' ■ ■ ■ i ■ ■' ■ i1 ■ • ■ i' ■ ■ n/z-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 5.20 5.40 5.60 5.80

12764.D 060302.M Mon Jun 10 10:30:06 2002 Page 18

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