GCMS analysis results for unknown compounds, June 2002

NYC 9/11 Public Portal Document

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ata File C:\MSDCHEM\l\DATA\060702\12742.D Vial: 16 Icq On 7 Jun 2002 8:47 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 11 Boron trifluoride etherate Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

4.80 1.27 ug/L 837568 1,4-dichlorobenzene-d4 9.89

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7/2 2 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 1 3 Ethyl Chloride 64 C2H5C1 000075-00-3 1 4 Borane, trifluoro- 68 BF3 007637-97-2 1 Abundance Scan 293 (4.801 min): 12742.D (-291) (-) m/z 49.10 100.00% 49

5000

17 /rr77 rm 1 rrr -rrI" . 42 , 83 4.40 4.60 4.80 5.00 5.20 0—TTT 36,4.1 1144241*44 m/z 51.05 39.74% /z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 *=. Abundance #1099: Boron trifluoride etherate 31

59 5000 45 74 4.40 4.60 4.80 5.00 5.20 m/z 47.00 "... 10.36% 0- 15.25 ■ ' i ■ 1 4 39. i . — 66 HTH .81 93 127 '1 11 '' 11 ■ ■ ■' i • • ■ ‘ 11 ' 11 I'' ri ( 1 1 m/z-> 10 20 30 40 50 60 70 80 .90 100 110 120 130 Abundance #108005: Acetic acid, chloro-, ethyl ester 29 11 ■ ■111 ■ ■ ■11 1 ■ ■ ■ i1 • ■ ■ ।1 ‘ 4.40 4.60 4.80 5.00 5.20 5000 83.00 8.17% 77 42 49 14 0- -4 20 ++35 30 —40 i> . m — i 59 65 | 80 88 94 107 122 90 100 110 120 130 1 ' • I i । ( i ( H'l i । i i 1’17 13111111111 miz-> 10 50 60 70 Abundance #107943: Ethyl Chloride ' i 1 1 ' ‘ i 1 1 ' • i ' ■ ‘ ■ i ' ‘ 23 4.40 4.60 4.80 5.00 5.20 m/z 42.00 7.55% 64 5000

49 15 35 0 ... I, ■ i ■1 H ■ i ■1111''11111 ■11 ■1 ■ ■ i ‘ ■1 ■ i ■ ■ ■ ■ i' m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 4.40 4.60 4.80 5.00 5.20

12742.D 060302.M Mon Jun 10 11:26:41 2002 Page 14

NYC-WT C_000015329