GCMS analysis results, sample AE12477, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052902\12477.D Vial: 19 Acq On : 30 May 2002 12:45 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Miso Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98. L ********************************************************************* Peak Number 8 Acetic acid, chloro-, ethyl... Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 3.98 2.29 ug/L 1382250 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 2 2 Borane, trifluoro- 68 BF3 007637-07-2 1 3 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 1 4 Ethyl Chloride 64 C2H5C1 000075-00-3 1 Abundance Scan 153 (3.978 min): 12477.D (-152) (-) m/z _ 49.10 100.00% 49

5000 84 36 43 3.60 3.80 4.00 4.20 4.40

n/z-> 0 0- —P 10 .... 30 20 40 50 IP 60 70 80 90 100 । * 1 1 * i * * * * । ‘ * * * । * * * * i * * 110 120 130 m/z 84.00 28.42% Abundance #108005: Acetic acid, chloro-, ethyl ester 29

5000 3.60 3.80 4.00 4 20 4.40 77 42 49 m/z 43.10 12.57% 14 \

miz-> 0 o-— 10 20 ++35—40 50 60 70 80 90 100 110 120 130 30 444 T 59PPITT 65 88 94 ‘ 11 I • • ■ • । • ,-i • । < ■ 107 122 11**11*1

Abundance #12321: Borane, trifluoro- 49 3.60' 3.80 4.00 4.20 4.40 ‘ 5000 m/z 44.05 10.99%

11 19 30 38 68 0- ■ ■ ■ ■ I ■ • • ■ i ■ ■ ■ ■ I ■ ■ ■ ■ i • ■ nz-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #1099: Boron trifluoride etherate 1 i ■ 1 ■ ■ i ■ ' • ■ i ■ ■ • ■ i 1 * ■ ■ i ■ 1 31 3.60 3.80 4.00 4.20 4.40 m/z 86.95 8.88% 59 5000 45 74

m/z-> 0- 0 —1525 ,, ,39l|l,l,.| TBTT 10 20 30 40 50 60 66 THTT 70 81 93 ‘'I1‘‘'1111‘I 111 1 I ' 1 ‘ ‘ I ' ‘ ' • I ' ‘ 80 90 100 110 120 127 130 3.60 3.80 4.00 4.20 4.40

12477.D 052202 .M Mon Jun 03 11:39:28 2002 Page 11

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