GCMS sample AE11905 results, June 6 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\060402\11905.D Vial: 8 Acq On 4 Jun 2002 9:33 pm Operator: McLean Sample 6/4 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 8 Acetic acid, chloro-, ethyl... Concentration Rank 7. R.T. EstConc Area Relative to ISTD R.T.

3.96 0.60 ug/L 405265 1,4-dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 2 2 Ethanol, 2,2-dichloro- 114 C2H4C120 000598-38-9/2 3 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 2 4 Borane, trifluoro- 68 BF3 007637 -07-2 1 Abundance Scan 150 (3.960 min): 11905.D (-148) (-) m/z 49.10 100.00% 49

5000 84 42

35 360 3.80 4.00 4.20 4.40

nz-> 0- ' ■ ।1 111 i rr ■ ■ । 111' । 10 20 30 40 50 1..—60 70..80 90 100 110 120 130 m/z . 84.00 36.61% Abundance #108005: Acetic acid, chloro-, ethyl ester 29

5000 77 360 3.80 4.00 4.20 4.40 42 49 m/z 42.10 27.21% 14

niz-> 0-- 10 20 30 +35—40 11.159 50 60 65 | 88 94 70 107 122 ■ ■1 |1. . . । . i . . । . 1111 • ■ > • । 80 90 100 110 120 130 • i • • ।.... 11... । 11

Abundance #1082: Ethanol, 2,2-dichloro- 31

360 3.80 4.00 4.20 4.40 5000 m/z 86.90 26.21%

25 , 37 43 49 55 61 70 77, 83 96 103 114 0- ■ 1 I 1 1 ■ 1 I 1 1fti 1———TTr T-n-T-rtYrVT-rprTT-rTTT-TT^^ m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #1099: Boron trifluoride etherate 31 360 3.80 4.00 4.20 4.40 m/z 82.95 20.09%

Ww 59 5000 45 74 Ww 0 15 1 1 I 21 , 254, +394 1++ 66 , 81 93 127 ■111 1 ■ ■ i ■ ■ ■ ■ i ' 1 ■ ■ i ■ ■ ■ ■ I 11 i m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 3.60 3.80 4.00 4.20 4.40

11905.D 060302 .M Wed Jun 05 14:03:51 2002 Page 11

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