GCMS analysis results for unknown compounds, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\060702\12737.D Vial: 13 Acq On 7 Jun 2002 6:21 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 Perdeuterobenzene Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 3.88 1.77 ug/L 978613 1,4-dichlorobenzene-d4 9.89 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Perdeuterobenzene 84 C6D6 001076-43-3 A 2 Furan, 2,3-dihydro-4-methyl- 84 C5H80 034314-83-5/ 9 3 2-Butenal, 3-methyl- 84 C5H80 000107-86-8 9 4 2-Butenal, 2-methyl- 84 C5H80 001115-11/3 9 Abundance Scan 136 (3.878 min): 12737.D (-134) (-) m/z 84.00 10/0.00% 84

5000 49 88 36

3.60 3.80 4.00 4.20 ol 118 i • • “ i" " i" “ i ■ “ • i ■■ ■ ■ i 1' I “ “ I “ “ I “ ’ ) "’ ’I I’ II’T m/z 49.10 42.57% n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33650: Perdeuterobenzene 84

5000 3.60 3.80 4.00 4.20 52 56 m/z 87.95 37.00% 42

mfe-> Abundance 12 ol TIITEmgdynT 18 28 38 24--H4+ ,62.s6..,72.76.80 5 10 15 20 25 30 35 40 45 50 55 60 ■ 65 70 75 80 85 90 95 #33672: Furan, 2,3-dihydro-4-methyl- 55 84 MMkois 3.60 3.80 4.00 4.20 5000 41 m/z 36.00 29.83% 29 69 1518 26 | 38 44 44 51 51 65 |

niz-> 01TTITTTTTTTTTTTHTTTTT HHH+ HTgH 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 81

Abundance #33657:2-Butenal, 3-methyl- 84 ‘ 3.60 3.80 4.00 4.20 ' 55 m/z 82.00 19.80% 41 5000 29

n/z-> 26 0 mPmDTTTTTT - P" — , , 44 ll iil 38 । 59 65 69 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ‘ i ‘11 * 1 *1 3.60 3.80 4.00 4.20

12737.D 060302.M Mon Jun 10 11:23:56 2002 Page 6

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