GCMS reference analysis for sample AE12224, June 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

» Data File C:\HPCHEM\l\DATA\JUN0302\REFl.D Vial: 4 Acq On 3 Jun 2002 11:39 am Operator : Morgan Sample gc/ms scan 5/31 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Jun 3 14:21 2002 Quant Results File:GCMS0531 .RES .

Quant Method : C:\HPCHEM\1\METHODS\GCMS0531.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri May 31 09:43:55 2002 Response via : Initial Calibration DataAcq Meth : GCMS0531

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.06 152 517258 40.00 ug/1 -0.01 10) Naphthalene-d8 15.70 136 2075117 40.00 ug/1 -0.01 17) Acenaphthene-diO 21.00 164 983568 40.00 ug/1 0.00 30) Phenanthrene-diO 25.43 188 1534491 40.00 ug/1 0.00 38) Chrysene-dl2 33.47 240 905837 40.00 ug/1 -0.03 44) Perylene-dl2 37.66 264 546720 40.00 ug/1 -0.02

System Monitoring Compounds 28) TCMX 23.14 209 202941 29.82 ug/L -0.01 Spiked Amount 40.000 Recovery 74.55% Target Compounds Qvalue 2) N-nitrosodimethylamine 5.72 74 142330 8.98 ug/1 99 3) bis(2-Chloroethyl)ether 11.47 93 270610 13.08 ug/1 99 4) 1,3-Dichlorobenzene 11.96 146 240202 11.69 ug/1 98 5) 1,4-Dichlorobenzene 12.11 146 253507 11.39 ug/1 99 6) 1,2-Dichlorobenzene 12.62 146 246804 12.60 ug/1 98 7) 2,2'-oxybi s(1-Chioropropan 12.96 45 441534 13.66 ug/1 99 8) N-Nitrosodi-n-propylamine 13.33 70 191727 13.41 ug/1 99 9) Hexachloroethane 13.47 117 77703 8.84 ug/1 96 11) Nitrobenzene 13.74 77 244628 12.77 ug/1 99 12) 1sophorone 14.40 82 550490 15.31 ug/1 99 13) bis(2-Chloroethoxy)methane 15.08 93 319746 13.54 ug/1 99 14) 1,2,4-Trichlorobenzene 15.58 180 204281 12.70 ug/1 99 15) Naphthalene 15.76 128 794181 14.54 ug/1 100 16) Hexachlorobutadiene 16.30 225 68412 9.66 ug/1 98 18) Hexachlorocyclopentadiene 18.49 237 37187 6.16 ug/1 100 19) 2-Chloronaphthalene 19.25 162 411104 15.69 ug/1 99 20) Dimethylphthalate 20.35 163 499361 15.00 ug/1 99 21) 2,6-Dinitrotoluene 20.56 165 98904 13.15 ug/1 97 22) Acenaphthylene 20.52 152 641588 13.65 ug/1 99 23) Acenaphthene 21.08 153 433120 15.30 ug/1 99 24) 2,4-Dinitrotoluene 21.73 165 121144 13.76 ug/1 98 25) Diethylphthalate 22.48 149 512282 16.61 ug/1 99 26) 4-Chlorophenylphehylether 22.63 204 227192 15.49 ug/1 99 27) Fluorene 22.60 166 471140 16.38 ug/1 100 2 9) Azobenzene 23.09 77 512887 13.46 ug/L 99 31) N-Nitrosodiphenylamine 23.02 168 202295 18.05 ug/1 98 32) 4-Bromophenylphenylether 24.09 248 116766 15.17 ug/1 97 33) Hexachlorobenzene 24.52 284 134368 15.94 ug/1 99 3 4) Phenanthrene 25.50 178 680489 15.78 ug/1 99 (#) = qualifier out of range (m) = manual integration REFl.D GCMS0531.M Mon Jun 03 14:30:33 2002 Page 1

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