GCMS reference analysis report sample AE12094, June 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\MAY3102\REFAl.D Vial: 14 Acq On 1 Jun 2002 12:47 am Operator: Morgan Sample gc/ms scan 5/30 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Jun 3 11:29 2002 Quant Results File:,GCMS0531.RES « e- Quant Method : C:\HPCHEM\1\METHODS\GCMS0531.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri May 31 09:43:55 2002 Response via : Initial Calibration DataAcq Meth : GCMS0531

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 12.06 152 519699 40.00 ug/1 -0.02 10) Naphthalene-d8 15.70 136 2094747 40.00 ug/1 -0.02 17) Acenaphthene-diO 20.99 164 1007432 40.00 ug/1 0.00 30) Phenanthrene-diO 25.43 188 1580567 40.00 ug/1 0.00 38) Chrysene-dl2 33.48 240 1014478 40.00 ug/1 -0.03 44) Perylene-dl2 37.66 264 660624 40.00 ug/1 -0.03 System Monitoring Compounds 28) TCMX 23.13 209 216748 31.10 ug/L -0.02 Spiked Amount 40.000 Recovery 77.75%

Target Compounds Qvalue 2) N-nitrosodimethylamine 5.73 74 154016 9.68 ug/1 97 3) bis(2-Chloroethyl)ether 11.46 93 292553 14.07 ug/1 98 4) 1,3-Dichlorobenzene 11.97 146 265643 12.86 ug/1 99 5) 1,4-Dichlorobenzene 12.11 146 284175 12.71 ug/1 99 6) 1,2-Dichlorobenzene 12.62 146 276805 14.06 ug/1 100 7) 2,2'-oxybis(1-Chloropropan 12.95 45 477791 14.71 ug/1 99 8) N-Nitrosodi-n-propylamine 13.34 70 209541 14.59 ug/1 98 9) Hexachloroethane 13.47 117 86238 9.76 ug/1 94 11) Nitrobenzene 13.74 77 274370 14.19 ug/1 98 12) 1sophorone 14.39 82 609697 16.80 ug/1 99 13) bis(2-Chloroethoxy)methane 15.08 93 354177 .14.86 ug/1 97 14) 1,2,4-Trichlorobenzene 15.59 180 228654 14.08 ug/1 98 15) Naphthalene 15.75 128 882705 16.01 ug/1 100 16) Hexachlorobutadiene 16.30 225 74984 10.49 ug/1 99 18) Hexachiorocyclopentadiene 18.49 237 23742 3.84 ug/1 98 19) 2-Chloronaphthalene 19.25 162 464777 17.32 ug/1 99 20) Dimethylphthalate 20.35 163 579976 17.01 ug/1 99 21) 2,6-Dinitrotoluene 20.56 165 117744 15.29 ug/1 98 2 2) Acenaphthylene 20.52 152 720678 14.97 ug/1 100 23) Acenaphthene 21.09 153 481440 16.60 ug/1 99 24) 2,4-Dinitrotoluene 21.73 165 145247 16.11 ug/1 99 25) Diethylphthalate 22.48 149 582619 18.44 ug/1 100 26) 4-Chlorophenylphenylether 22.63 204 257300 17.13 ug/1 98 27) Fluorene 22.60 166 536896 18.23 ug/1 99 29) Azobenzene 23.10 77 584187 14.97 ug/L 95 31) N-Nitrosodiphenylamine 23.02 168 207876 18.01 ug/1 96 32) 4-Bromophenylphenylether 24.10 248 130921 16.51 ug/1 95 33) Hexachlorobenzene 24.52 284 153418 17.67 ug/1 96 3 4) Phenanthrene 25.49 178 774890 17.44 ug/1 100 (#) = qualifier out of range (m) = manual integration REFAI.D GCMS0531.M Mon Jun 03 11:31:08 2002 Page 1

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