GCMS analysis results, sample AE12478, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052902\12478.D Vial: 20 Acq On : 30 May 2002 1:34 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number- 8 Acetic acid, chloro-, ethyl... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 3.99 0.42 ug/L 297027 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 2 2 Ethanol, 2,2-dichloro- 114 C2H4C120 000598-38-9 l 3 Ethanol, 2,2,2-trifluoro- 100 C2H3F30 000075-89-8/1 4 Ethanol, 2,2,2-trifluoro- 100 C2H3F30 000075-89/8 1 Abundance Scan 156 (3.996 min): 12478.D (-154) (-) m/z 49.10 1.00.00% 49 84 5000

35 . ■ 3.60 3.80 4.00 4.20 4.40

n/z-> 01 — 10 ... 20 ^I.. 30 40 50 ......................... 1 60 70 80 • ■ i ’ *' ■ i • 1 ‘ ‘ i • 90 100 110 120 130 m/z . 84.00 61.11% Abundance #108005: Acetic acid, chloro-, ethyl ester 23

5000 ■ i ■ 1 ■ ■ i ‘ ■ 1 i ■ • * ' i ■ •

77 3.60 3.80 4.00 4.20 4.40 42 49 m/z 50.00 26.94%

miz-> 0+ araalasa 10 14

20 . 35 TBn 30 40 1,6,0,159.65., 111| 1 • ■ >88■ ।। 50 60 70 80 94 90 107 122 (111 ■.. ।. 100 110 120 130 Abundance #1082: Ethanol, 2,2-dichloro- 31 —■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ • ■ i ‘ ■ i ■ ■ 3.60 3.80 4.00 4.20 4.40 5000 m/z 85.00 19.31%

Of " I' “ ' I' 25, 37 43 49 55 61 70 77, 83 ■ l-lll 11" ■ ■ i ■ ■ 1 1114/4 . । 96 103 114 । , i i . ।। . niz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #108306: Ethanol, 2,2,2-trifluoro- 31 3.60 3.80 4.00 4.20 4.40 m/z. 86.00 17.50% 5000

51 61 0- T-r-p-n-r-j-r 25 23,1 44 „| ■ ‘ 1 ! 11 ■ ■ l ■ 1 ■ ‘'I1' " ■ I 69 ■ I ' ' ‘ rl 81 99 ‘ I ' ■ ‘ ‘ I 1 • ‘ ‘ I ' ‘ ' 1 ' ■ ‘ ‘ I ‘ m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 3.60 3.80 4.00 4.20 4.40

12478.D 052202.M Mon Jun 03 11:40:32 2002 Page 11

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