GCMS analysis results, sample AE12479, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052902\12479.D Vial: 21 Acq On : 30 May 2002 2:22 am Operator: McLean Sample : gc/ms scan 5/28 fb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C: \DATABASE\NIST98 . L ********************************************************************* Peak Number 8 Acetic acid, chloro-, ethyl... Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 3.94 1.50 ug/L 1039700 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 9 2 2-Chloroethanol 80 C2H5C1O 000107-07-3/2 3 Ethyl Chloride 64 C2H5C1 000075-00-3 2 4 1-Propanol, 3-chloro-94 C3H7C10 000627-30-5 2 Abundance Scan 147 (3.943 min): 12479.D (-145) (-) m/z 49.10 /100.00% 49

5000 t

1*1/d//n/n/n//n1//—nnn—n/n. 86 Ot .......... 354|| / 1 I 0 3.60 m/z 3.80 51.10 4.00 4.20 52.91%

_/ww ‘ 4 I ‘ ‘ ‘ I 4 ‘ ‘ ‘ I * ‘ ‘ ‘ 1 * 1 ' * I1‘ * >। • * * * i * niz-> Abundance 10 20 30 40 50 60 70 80 90 100 #108005: Acetic acid, chloro-, ethyl ester 110 120 130 MMws 23

5000 ‘ ■ i ■ ■ ■ ■ i ‘ ‘ ‘ ■ i 1 1 ■ ■ i • ■ ■ ' i ■

77 3.60 3.80 4.00 4.20 42 49 m/z 44.10 18.20% 14

miz-> 01 -ll 10 20 30 35 BTp — 40 !■„.! . 59 65 TBU 50 60 70 | 80 88 94 90 —U—m 100 107 110 122 120 130 Abundance #108296:2-Chloroethanol 31 ■ • । ■ i *11 ■ r ■ • ‘ ■ i j ■ 11 3.60 3.80 4.00 4.20 5000 m/z 47.10 14.44%

15 37 43 49 55 61 or 80 miz-> 01 112, 1Tepr A1aw-a**-***11 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #107943: Ethyl Chloride ' 1 i ‘ ■ i ■ • ■ • i ‘ ■ i ‘ ■ i ■ 23 3.60 3.80 4.00 4.20 m/z 48.05 13.83%

5000

35 49 64 L/MHMahat 15

n/z-> 0 ir 141, 1 I '1 10 20 30 --4 40 50 60 70 80 90 100 110 120 130 ■ i • ■■ ' 1 i ‘ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ' ■ i ■ ■ ‘ ■ i • ■ ■ ■ i ■ ‘ I’* I i i i i । । i i i । । । i । । t 3.60 3.80 4.00 4.20

12479.D 052202.M Mon Jun 03 11:41:47 2002 Page 11

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