GCMS analysis results for sample AE11928, June 2002

NYC 9/11 Public Portal Document • Library Search Compound Report

Data File : C: \MSDCHEM\ 1 \DATA\052302\11928.D Vial: 8 . Acq On : 23 May 2002 3:40 pm Operator: Mclean Sample : 5/22ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 6 l-Buten-3-yne, 2-chloro- Concentration Rank 2

R.T. EstCono Area Relative to ISTD R.T.

3.96 3.62 ug/L 2647230 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qua'

1 l-Buten-3-yne, 2-chloro- 86 C4H3C1 017712-36-6/9 2 Phosphonic difluoride 86 F2HOP 014939-34-5 5 3 Ethenamine, N-methyl-N-nitroso- 86 C3H6N20 004549-40-0 5 4 2-Butenal, 3-methyl- 84 C5H80 000107-86-8 4 Abundance Scan 150 (3.961 min): 11928.D (-149) (-) m/z 86.00 100.00% 85

43 5000

40 47 ■ ■ । 3.60 ■ 1 । ■ ■ ■ ■ । ■ ■ ■ ' । 3.80 4.00 4.20 ■ i ■ 4.40

niz-> 20 25 Of * 30 35 40 45 50 .,.1.1................... 11182 1 55 60 65 70 75 80 85 90 95 i Tp-n-r-p- m/z .84.00 54.74% Abundance #34744: 1-Buten-3-yne, 2-chloro- 51 85

5000 3.60 3.80 4.00 4.20 4.40 m/z 43.10 52.58% Oh 11111141111111111711/11111313 60 miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 39 + 11 A/wuoot Abundance #34889: Phosphonic difluoride 85

3 60 3.80 4.00 4.20 4.40 5000 69 m/z 88.00 38.54%

31 47 Oh T-rp- ■ • ■ i1 “ ■ i ■1 ■ ■ i " ■ ■ i ■ miz-> 20 25 3035404550556065 70 75 8085 90 95 50 66

• * i * ■ “ i * * “ । i ■ " • i1 ■ ■ ■ i ■ ■ -n-p-n-r-p-r wMMMas Abundance #737: Ethenamine, N-methyl-N-nitroso- 30 42 360 3.80 4.00 4.20 4.40 m/z 47.10 13.81% 5000 57 20 67 80 83 86 miz—> Oh * • I ‘' ,1333811 1,47.51*1 +1’ ' " 1111 ^1" " 1" " 1111' 11" 11' ■ “ r1 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20 4.40

11928.D 052202.M Wed May 29 09:48:47 2002 Page 9

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