GCMS analysis report sample AE09682, May 23, 2002

NYC 9/11 Public Portal Document Llbrary aearen compound Report Data File : C:\MSDCHEM\l\DATA\052102\9682.D Vial: 18 Acq On : 22 May 2002 3:11 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 5 l-Buten-3-yne, 1-chloro-, (Z)- Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

3.92 1.00 ug/L 707593 1,4-Dichlorobenzene-d4 9.90

Hit# of

1 2 5 Tentative ID l-Buten-3-yne, 1-chloro-, (Z)- l-Buten-3-yne, 1-chloro-, (E)- MW

86 86 MolForm

C4H3C1 C4H3C1 CAS# 020374-90-7(83 ) 020374-91-8 83/ P 3 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3 9 4 l-Buten-3-yne, 1-chloro-, (Z)- 86 C4H3C1 020374-90-7 9 Abundance Scan 144 (3.925 min): 9682.D (-142) (-) m/z 51.10 100.00% 51

5000 43 47 86 ./Mmunat 35 39 ■ ■ ■ i ■ ■ ■ ■ i • ■ ■ ■ i ■ ■ • ■ i ■ ■ ■ ‘ i 3.60 3.80 4.00 4.20 83 0- ■ i ‘ '11 ■ ‘ ‘11 ■ ■' ■ I m/z 86.00 67.16% •nfe-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #111070: 1-Buten-3-yne, 1-chloro-, (Z)- 51 86

5000 ■ ■ ■ i ‘ ' ■ ■ i ■ ■ ■ ■ i • ■ ■ ■ i ■ ■ ■ ■ i 3.60 3.80 4.00 4.20 m/z 43.10 56.54%

niz-> 0- 30 35 40 45 50 55 60 65 70 . 75 80 60 85 +87 MM""yyMMMMMWyAWWir—n 90 95 Abundance #12408:1-Buten-3-yne, 1-chloro-, (E)- 51 85 T 3.60 3.80 4.00 4.20 5000 m/z 47.05 46.73%

0- . 60 ' ■ i'1 ■ ■ I'' ■ ■ i ■'' ■ i ■ ■ ■ ■ i ‘ ■ i ■ ■ ■11 +8010 wMdws m/z-> 30 35 40 45 5o 55 60 65 70 75 80 85 90 95 Abundance #12404: 1,2,3-Butatriene, 1-chloro- ' ■ ■ i ■ ■ ■ ■ i ■ ■ 1 ■ i ■ 1 ■ ■ i ■ ■ ■ ■ i 51 86 3.60 3.80 4.00 4.20 m/z 39.10 27.45% 5000

1 n/z-> 0 1 ■ 1111' i1 ■ • ■ i ■ ■ ■ ■ I'111 30 35 40 45 50 . —ptt IImTT । rr. . । 55 60 60 65 70 75 ri । ... I | 80 85 +89— —— 90 95 3.60 3.80 4.00 4.20

9682.D 052202.M Wed May 22 11:46:47 2002 Page 7

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