GCMS analysis report sample AE09678, May 23, 2002

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Data File : C:\MSDCHEM\1\DATA\052102\9678.D Vial: 16 Acq On : 22 May 2002 1:33 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 14 6-Ethyl-5-[1-piperidinyl]-2... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T.

35.38 0.34 ug/L 120199 Perylene-d12 34.66

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 6-Ethyl-5-[1-piperidinyl]-2,4-py... 221 C11H19N5 1000212-52-9 9 2 Ethane, 1-(4,4,4-trifluoro-l,3-d... 308 C5H6F6S4 1000226-87-3 9 3 Trisiloxane, 1,1,1,5,5,5-hexamet... 384 C12H3604Si5 003555-47-3 9 42-(Acetoxymethyl) -3-(methoxycarb... 282 C17H14O4 093103-70/9 9 Abundance Scan 5497 (35.377 min): 9678.D (-5491) (-) m/z73.10 100.00% 73 221 147

281

MrwrtwmyMyMeya 5000 355 44 429 96 0- 1 I 35 00 35.20 35.40 35.60 35.80 m/z 221.10 93.33% mfe-> 50 100 150 200 250 300 350 400 Abundance #87832:6-Ethyl-5-[1 -piperidinyl]-2,4-pyrimidinediamine 221 43 164 5000 137 3500 35.20 35.40 35.60 35.80 84 m/z 147.05 76.80% 110 I 192 0- 44— +4414—— n/z-> 50 100 150 200 250 300 350 400 Abundance #84757: Ethane, 1-(4,4,4-trifIuoro-1,3-dithiobutyl)-2-(3,3... 207 106 4 35.00 35.20 35.40 35.60 35.80 5000 m/z 207.00 56.67% 69 147 । i i -1 1., fJ — 175 1, 1. 308 0- ■ । • 11d—n—d./*/*/**1——0—dg miz-> 50 100 150 200 250 300 350 400 Abundance #26961: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trime... 73 147 35.00 35.20 35.40 35.60 35.80 m/z 281.00 48.93% 281 5000

369 MAd n/z-> 0 apo 100 45

50 95 117 1/1,17 f.207226 249, . [ 310 341 ["h -Ti" mridi 150 200 250 1 ‘ I 300 I—' ' ' 350 I [ ' r ' r-j—r 400 ■ I" 1 1 ‘ ■ ' i ■ ■ ■ ■ i ■ 1 ' ‘ i ■ 35.00 35.20 35.40 35.60 35.80

9678.D 052202.M Wed May 22 11:43:34 2002 Page 17

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