GCMS analysis report sample AE09519, May 23, 2002

NYC 9/11 Public Portal Document Llprary searcn compound Keporc Data File : C:\MSDCHEM\l\DATA\052102\9519.D Vial: 14 Acq On : 21 May 2002 11:55 pm Operator: Mclean Sample : re-extract Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 1,3,5-Cycloheptatriene Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 4.27 2.41 ug/L 1438350 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 5 2 Spiro[2.4]hepta-4,6-diene 92 C7H8 000765-46-8/5 3 Bicyclo [3.2.0] hepta-2, 6-diene 92 C7H8 002422-86-8 4 4 1,6-Heptadiyne 92 C7H8 002396-63-6 4 Abundance Scan 203 (4.272 min): 9519.D (-198) (-) m/z 91.10 00.00% 91

5000 47 65 1 /z—> Abundance 0 i ■ ■' ■ i ■ “ ■ i ■ ■ ■' i + +58—44 39 43

15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 82 J । 87 <*i****i“* ■ । >।*11111 TTtt ‘ 1+4441’1 m/z 4.00 4.20 92.10 4.40 4.60 94.90% #117298: 1,3,5-Cycloheptatriene 91 ................. ............. 5000 4.00 4.20 4.40 4.60 39 65 m/z 47.10 30.20%

n/z—> Abundance 0 +4+L3? 28 1 45 51 611 73 77 86 , 111 H111111 [ 111111111111 u ft 111 f HT 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 #37322: Spiro[2.4]hepta-4,6-diene '■I'.■■ !■ ■ "4. TMa VP Ml

91 ■ ■ ■ ■ i ■ ■ • ■ i ■ ■ ■ ‘ i ■ 1 ■ ‘ i ■ ■ • ■

"MHaahau 4.00 4.20 4.40 4.60 5000 m/z 88.00 17.85%

65 27 31 39 45 51 611 , 69 73 77 82 86 , 0 TTguhumHtnnm ।" 11111111 ‘11" i ■1" i' ■" i"' 11 — /z—> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #37273: BicycIo[3.2.0]hepta-2,6-diene 91 4.00 4.20 4.40 4.60 m/z 65.10 16.91% 5000

66 39

m/z-> 0: TH 27 51 m 1 “ “I“ ''I‘ ‘I"' 'I 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 “ i' “' i “ 4.00 4.20 4.40 4.60

9519.D 052202.M Wed May 22 11:32:34 2002 Page 7

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