GCMS pesticide analysis results, sample AE11573, May-June 2002

NYC 9/11 Public Portal Document aAt*y wMpoullt ACpVL w

Data File : C:\MSDCHEM\1\DATA\052902\11311RR.D Vial: 16 Acq On : 29 May 2002 2:39 pm Operator: Bohlk / Inst 213 Sample : SAMPLE 11311 RE-EXTD 5/23/02 Inst : Instrumen Mise Multipir: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1\5973N\052802.M (RTE Integrator) ene Title Library : Quantitation For Method 525.2 : C:\DATABASE\WILEY7N.L ********************************************************************** “d-lo Peak Number 13 [2.2](2,6)pyrazinophane Concentration Rank 1 1B R.T. EstConc Area Relative to ISTD R.T. 26.62 4.45 ug/L 5977940 p-Terphenyl d-14 27.39

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 [2.2](2,6)pyrazinophane 123624-86-2 64 212 C12H12N4 2 [1,1'-Biphenyl]-4,4'-diamine, 3,... 212 C14H16N2 000612-82-8 64 3 [1,1'-Biphenyl]-4,4'-diamine, 3,... 212 C14H16N2 000119-93-7 59 4 Benzenamine, 2-methoxy-N-(4-pyri... 212 C13H12N20 041855-68-9 59 Abundance Scan 1714 (26.622 min): 11311RR.D (-) m/z 212.20 100.00% 2 2

5000

106 . 26.40 26.60 26.80 27.00 52 66 78 0- ■ • i ■ ■ ■ ■ 11 ■ 1 11 11 92'11 Jf ThmmehenTt" 124 138 156168 180 194 „ m/z 106.10 21.08% n/z-> 20 40 60 80 100 120 140 160 180 200 220 Abundance #132924: [2.2](2,6)pyrazinophane 2 2

5000 ■ 1111' n 1111 ■ 111 26.40 26.60 26.80 27.00 m/z 213.20 16.69% 158 185 144 171 I '197 ■n/z-> L L OU • i' • • • i1 ■ ‘ • i ■ ■ ■ ■ i ■ ■ •' i ■ • ■11 • ■ ■ • i111 ■ i • • I■ • iI,r TonCT 20 40 60 80 100 120 140 160 180 200 220 Abundance #133761: [1,1’-Biphenyl]-4,4’-diamine, 3,3’-dimethyl-, dih... 212

26.40 26.60 26.80 27.00 5000 m/z 211.20 16.45%

106 130 152 168180 196 O-r ■ i ■ • ■ ■ 42 77 i11' ■ i ■ ■' ‘ i ■ ■ ■ • i ■ ■ •' i • ■ • • i' mmmp m/z-> 20 40 60 80 100 120 140 160 180 200 220 Abundance #133756: [1,1‘-Biphenyl]-4,4‘-diamine, 3,3‘-dimethyl- $$ B... 212 26.40 26.60 26.80 27,00 m/z 208.20 16.13%

5000

106 .

mz—> . . 51 65 77 91 ] 118130 152 168120 T 0*i । H । ■ ’pi । ri । r r । r । mpdrin rTFri p T “W"rrPr""T 20 40 60 80 100 120 140 160 180 200 220 I T ■■1 nF 26.40 26.60 26.8027.00

1311RR.D 052802.M Mon Jun 03 15:50:28 2002 Page 15

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