GCMS calibration data for TCLP analysis, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\MAR2502\4385.D Vial: 12 Acq On : 25 Mar 2002 9:03 pm Operator: Sample : gc/ms scan 2/28 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Cyclopentasiloxane, decamethyl Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

14.85 1.02 ug/1 172355 Naphthalene-d8 15.88

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopentasiloxane, decamethyl-' 370 C10H3005Si5 000541-02-6 91 2 3,4-Dihydroxybenzyl alcohol, tris (tr 356 C16H3203Si3 068595-79-9 49 3 N-(Trifluoroacetyl)-N,0,0',O'1-tetr 553 C22H42F3NO4Si4 000000-00-0 43 4 Benzoic acid, 2,4-bis[(trimethylsil 370 C16H30O4Si 3 010586-16-0 37 Abundance Scan 1068 (14.847 min): 4385.D (-) | m/z 73.00 100.00% 73 I

5000 267 355 ■ • i ■ ■ i ■ 1 ‘ • i ■ ‘ 45 14.60 14.80 15.00 15.20 m/z-> I 50 .100 ,.154.4123.237,1.. 108 150 200 250 300 323 i • • 350 400 450 500 550 m/z 267.00 4 6.20% Abundance #51266: Cyclopentasiloxane, decamethyl- 70 355 267 . ............................. , , , , , 5000 1 14.60' 14.80 15.00 15.20 m/z 355.05 45.37% 207 323 ■ ■ । ■ mz-2 50.. 100. 150_ 200_ 250 300 .. ...350 2 400 450 500 550 Abundance s ■ ;• , T 73

14.60 14.80 15'00 15.20 ' 267 5000 179 m/z 356.0,5 16.34% 356 45 147 209 237 312 m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #60162: N-(Trifluoroacety)-N,O,O’,0"-tetrakis(rimethylsi 73 14.60 14.80 15.00 15.20 m/z 268.0,0 12.64% 355 5000

45

miz-> 450 147 193 100 150 200 250 267 300 350 400 450 500 538 550 1 1 14.60 14.80 15.00 15.20

4385.D GCMS0308.M Thu Mar 28 12:28:53 2002 Page 1

NYC-WTC_000011939