GCMS calibration table for TCLP method, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\MAR0102\3283.D Vial: 43 Acq On 3 Mar 2002 5:38 am Operator: Sample gc/ms scan 2/4 fb Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Silane, tetramethyl- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.19 1.66 ug/1 355044 1,4-Dichlorobenzene-d4 12.31

Hit# of 5 / Tentative ID MW MolForm CAS# Qual

1 Silane, tetramethyl- 88 C4H12S1 000075-76-3 37 2 N-Ethylformamide 73 C3H7NO 000627-45-2 9 3 1-Butanamine, 3-methyl- 87 C5H13N 000107-85-7 9 4 1,3-Dioxolane, 2-methyl- 88 C4H802 000497-26-7 7 Abundance Scan 343 (8.191 min): 3283.D (-) m/ z 73.00 100.00% 73

5000 43 - ■ i ■ ‘ ' i ■

55 87 103 7.80 8.00 8.20 8.40 8.60

m/z-> ■ ' i ‘ 10 ' ‘ i 20 )i 30 38,1111, 40 50 67,1 H ■ i • ■ ■ > j ■ ■ ■ • | • 60 70 80 90 100 110 m/z 42.95 28.69% Abundance #62932: Silane, tetramethyl- 73

5000 7.80 8.00 8.20 8.40 8.60 45 m/ z 41.05 10.35% 15 | 53 59 । • ■ i ' ‘ i ■ ‘ ‘ ■ i 1 ITITT ■ ■ i ■ ■ • 88 ■ i ■ ■ ■ ■ i ■ ‘ ■ i ■ m/z-> 10 20 30 40 50 60 70 80 ' 90 100 110 Abundance r ' < Ggformemide 30 73 . r 1' i i i j i r

7.80 8.00 8.20 8.40 8.60 5000 m/z 44.95 10.32? 44 58 15 I*** ‘ ■ i • ■ ' ‘ i ■ ■ ■ ‘ i ■ ' ■ 1 i ■ ■ ■ ■ i 1 1 1 1 I 1 1 1 ' I ' m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #763: 1-Butanamine, 3-methyl- _________ _____ _______ 30 ' i ■ ' ■ ■ i • ■ ■ ■ i • ■ ■ ■ i ■ • ‘ ■ i ■ ■ 7.80 8.00 8.20 8.40 8.60 m/z 71.0.0 7.28 5000

15 41 , 55 70 87 1 1 i ' ''' 1 i 1 ' ■ r• < • • । • i.. ।।।।. 1111 i'i 111111111111 m/z-> 10 20 30___ 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

3283.D GCMS0208.M Mon Mar 25 12:19:09 2002 Page 1

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