GCMS analysis results for sample AE03075, March 5 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

■ 'Data. File : C:\MSDCHEM\l\5973N\02FEB28\02717.D Vial: 2 Acq On : 28 Feb 2002 3:30 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 28, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l..-\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 Cyclopropanecarboxylic acid... Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

3.99 0.05 ug/L 17400 1,4-Dichl oroben z ene - d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopropanecarboxylic acid $$ C... 86 C4H602 001759-53-1 3 2 (1-D)ethenol $$ Ethen-l-d-ol (CAS) 45 C2H3DO 090134-16-0 3 3 1-Butyne, 4-methoxy- 84 C5H80 036678-08-7 3 4 Cyclopropanecarboxylic acid (CAS... 86 C4H602 001759-53-1 3 Abundance Scan 55 (3.995 min): 02717.D (-) m/z 45.10 100.00% 45

5000 55 ........ f ...... AA ■ i • • ’ 1 i ■ 1 ■ • i ■ ■ ■ ■ i ■ ■ • • i ■ •

51 86 3.60 3.80 4.00 4.20 4.40 H 01 . t . . ., ,. .. . ।, , , . t , 1 , . i . !. > l . ( . . > . ।. .i!ti.11... ।... 11.. n |.... ] m/z 43.10 29.00% miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3761: Cyclopropanecarboxylic acid $$ Carboxycyclopropane... 39

5000 42 85 --AAAA-A 45 58 3.60 3.80 4.00 4.20 4.40 27 68 m/z 55 10 26.74%

0 11 ■ ■ “ i ■ • • ■ i" • ■ i' ■'' i 11 “ i1 i‘"‘i•" 'i■ m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #219:(1-D)ethenol$$Ethen-1-d-ol(CAS) 45 30 3.60 3.80 4.00 4.20 4.40 5000 m/z 85.90 10.86%

16 27 42 WMyhyhapus m/z-> 01TIT ... 13|...... II. NTggTTT 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 SO ] Abundance #3299:1-Butyne, 4-methoxy- —' I ■ ■ ‘ ' I ‘ ‘ I ‘ ‘ 1 1 I 1 ‘ ‘ ‘‘I 1 ‘ 45 3.60 3.80 4.00 4.20 4.40 m/z 51.00 5.91%

5000- 54 W 27 51 83 30 38 69 o- Tp-rrrp-rTTpT-rrp-rrrp- ”..... ..... • < 111»11 • * • ■ i ■ ■ ■' i ■ ■1111 ■ ■' l ■" ■ i • i ■ ■ • • i ■ 1 ■ ■ i ■ ■ ■ * i ■ ' 1 ‘ i • ■ mfe-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 3,60 3.80 4.00 4.20 4.40

02717.D HP022102.M Fri Mar 01 10:07:21 2002 Page 5

NYC-WTC_000010955