GCMS analysis report for sample AE01509, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report • Data File : C:\MSDCHEM\1\5973N\02FEB21\01509.D Vial: 1 Acq On : 21 Feb 2002 3 :10 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1. . .\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 3 METHYLFULVENE Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

4.39 0.06 ug/L 28844 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 METHYLFULVENE 92 C7H8 000000-00-0 4 2 Benzaldehyde, 4-benzyloxy-2-fluo... 246 C14H11FO3 141523-16-2 4 3 ETHINYLCYCLOPENTENE-(1) 92 C7H8 000000-00-0 4 4 1,3,5-Cycloheptatriene (CAS) $$ ... 92 C7H8 000544-25-2 4 Abundance Scan 90 (4.390 min): 01509.D (-) m/z 91.00 100.00% 91

5000

■ i 1 1 1 1 i ■ ■ ■ i ■ ' ■ * i • ‘ 49 65 4.00 4.20 4.40 4.60 4.80 04 ajlk nJ...,!. m/z 92.00 73.65% n/z-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #5531: METHYLFULVENE 91

5000 4.00 4.20 4.40 4.60 4.80 m/z 64.90 12.08% 39 65 0- .. ______ , ■ I ‘ ‘ ‘ 1 I ‘ ‘ ‘ ‘ I ' ' ■ ‘ I ‘ . j 11 * । । . . । ] . . ' I ' ‘ ' 1 I ' ‘ ‘ ' I ■ ' ‘ ‘ I ‘ ' niz-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #181229: Benzaldehyde, 4-benzyloxy-2-fluoro-5-hydroxy- 9ft ■ i 1 ■ ■ 1 i ■ ■ __4.00 4.20 4.40 ‘ 4.60 4.80 ______ 5000 m/z 49.00 7.87%

49 65 M-MW/wWhwMJAh miz-> 0- — 40 77 60 80 G 1" ' 100 120 140 160 180 200 220 246 240 Abundance #5532: ETHINYLCYCLOPENTENE-(1) ' i ■ ■ ■ 1 i ■ ■ 1 • i 1 ■ ■ ■ i 1 ' ■ • i 1 ■ 91 4.00 4.20 4.40 4.60 4.80 m/z 44.10 6.39%

5000 / 1A A

39 65 0J ‘ 4 m ' ra 1 " ■ i • 1 ' ' i ■ • ■ ■ i 1 1 ■ ■ i ‘ ■ i • • ■ ■ i > ■ • • i • ■ ■ ■ i • ■ .J i » I * » 1 i ■ • • • r■ r"1' m/z—> 40 60 80 100 120 140 160 180 200 220 240 4.00 4.20 4.40 4.60 4.80

01509.D HP022102.M Mon Feb 25 10:55:03 2002 Page 5

NYC-WTC_000010016