GCMS calibration analysis results, DEP Labs, Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\5973N\02FEB21\0123B.D Vial: 1 Acq On : 21 Feb 2002 10:46 am Operator: Sample : lab blank 1/23 Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 13 3,6-Dimethyl-triazolo(4,3-b... Concentration Rank 11

R.T. EstConc Area Relative to ISTD R.T.

24.86 0.02 ug/L 16304 Phenanthrene-dl0 22.64

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3,6-Dimethyl-triazolo (4,3-b)(1,2... 149 C6H7N5 000000-00-0 5 2 3,6-DIMETHYL-TRIAZOLO(4,3-B]-1,2... 149 C6H7N5 061139-71-7 5 3 2-(1-Methyl-2-pyrryl)imidazoline 149 C8H11N3 000000-00-0 4 4 Benzothiazole, 2-methyl- (CAS) $... 149 C8H7NS 000120-75-2 4 Abundance Scan 1903 (24.857 min): 0123B.D (-) m/z 149.00 100.00% 149

5000 —..............

41 207 24.60 24.80 25.00 25.20 I I O i " " I" ■ ‘ t" "I “ “ i" " i “ i 84 i • ■ ■ ■ i ‘ ■ ■■ i TTI 1***0* m/z 41.10 15.61% m/z—> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 Abundance #44984:3,6-Dimethyl-triazolo(4,3-b)(1,2,4)-triazine 149

5000 81 ‘ I ■ ■ i ■ ■ ■ ■ I 1 ' 24.60 24.80 25.00 25.20 41 53 m/ Z 207.00 12.00% 121 0- ■ ■ i ■" • ■ i । ■ ■" i TIPI i ■" ■ i ■■ “ ।" “ i1 “11 ■ ■" i ■ “ m/z-> 30 40 50 K) 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 Abundance #44967:3,6-DIMETHYL-TRIAZOLO[4,3-B]-1,2,4-TRIAZlNE $$ 1,2... 149 ■ ■ I • ■ 1 ■ i 1 ■ i • ■ ■ I ■ •

24.60 24.80 25.00 25.20 5000 81 m/z 150.00 10.70% 41 53 121 O- MMmmmHHHt I'1'111'1' I''111"'' I''111"1111'' m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 Abundance #45141:2-(1 -Methyl-2-pyrryl)imidazoline ■ ■ i ■ ■ • ■ i ■ 1 ■ i • ■ ■ ■ i ' ' 149 24.60 24.80 25.00 25.20 m/ Z 49.00 9.98% 5000 107 Awp A A \AM J 120

0- i" ‘ ■ i"1 ■ i1" ■ i ■11 ■ i ■ ‘ ■ ■ i" " i ■ “11" " i" " ■ ■ i ■ ■ ■ ■ I ■7 ■ ■ i ■ ■

n/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 24.60 24.80 25.00 25.20

0123B.D HP022102.M Mon Feb 25 10:54:38 2002 Page 15

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