GCMS calibration analysis results, DEP Labs, Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report * Data File : C:\MSDCHEM\l\5973N\02FEB21\0123B.D Vial: 1 Acq On : 21 Feb 2002 10:46 am Operator: Sample : lab blank 1/23 Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 12 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

22.28 0.12 ug/L 86603 Phenant hrene-d10 22.64

Hit# of 5 Tentative ID MW MolForm CAS# Qual

l 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 78 2 l-amino-2-methyl-4-isopropyl-thi... 192 C5H13N4PS 107264-54-0 50 3 N-(2-methylprop-2-enyl)-2-nitrob. .. 192 C10H12N2O2 000000-00-0 50 4 Benzo[1,2-c:3,4-c]bis(isothiazol ... 192 C8H4N2S2 074960-05-7 45 Abundance Scan 1675 (22.283 min): 0123B.D (-) m/z 192.00 100.00% 1912

5000

96 1.8 49 70 82 118 146 160 | 22.00 22.20 22.40 22.60 0- ---HH TWTTT .... al.... T.......... i1 m/z 96.10 17.48% m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102588:4-METHOXY-BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

108 5000- T 188 22.00 22.20 22.40 22.60 146 175 m/z 191.10 16.58%

01 ■ ■ i • ■ ■ ■ i ■ ■' • i ■ ■' ■ i ■ ■ ■ ■ i111 ■ i ■ " ' i ■ ■ i " " i ■ “ 11 ■ “11 “ 11 ■ ■ ■ ■ i " ■' i ■ tugni niz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #101918:1 -amino-2-methyl-4-isopropyl-thiotriazaphosphoIin... 159 192 y l * * ’ 22.00 22.20 22.40 22.60 m/z 146.10 13.37% 5000

177 a 144 0 “ i ■ ■ " i■•■■i■11' i" • • i ■ ■ “ i ■ ■" i‘1" IH'■i11 ■ ■ i1 “ ■ i ■ ■ > i ■ • L miz-> Abundance 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #102494: N-(2-methylprop-2-enyl)-2-nitrobenzenamine 1912 T 2 IT 22.00 22.20 22.40 22.60 l 77 151 m/z 193.10 12.87% 130 93 104 5000 119

177 0 1 ■ i ■ ■ “ I ■ “ 11" “ i “ " i “ " i TII’ ’I’- I’’ 111- ■ i • " ' i ■ ■" i1 ■ " i ■ ■' ■ i L ■ ............ ,................ r /z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.00 22.20 22.40 22.60

0123B.D HP022102.M Mon Feb 25 10:54:38 2002 Page 14

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