GCMS surrogate recovery data, Mar 13 2002

NYC 9/11 Public Portal Document LSLaLy DCalii ~upouli

Data File : C: \HPCHEM\1\DATA\FEB1502\1941.D Vial: 15 Acq On : 16 Feb 2002 5:02 am Operator: 209 GALOS Sample : re-extract Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 3-Pentanol, 3-methyl- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

8.21 0.29 ug/1 45443 1,4-Dichlorobenzene-d4 12.33

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Pentanol, 3-methyl- 102 C6H140 000077-74-7 33 2 2-Methyl-5-hiexen-3-ol 114 C7H140 032815-70-6 9 3 Pentane, 3 ethoxy- 102 C6H140 036839-67-5 9 4 2 -Butanone , 3-methoxy-3-methyl- 116 C6H1202 036687-98-6 9 Abundance Scan 345 (8.207 min): 1941.D (-) m/ z 73. 0,0 ’ 10 0.00% 73

5000 43

m/Z-2 i" " i" " i „8l4 49 55 59 ,, 87 103 THt 4 TIUTTTTNTTWTTTTTTTTTTTHTTTTT 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 j 7.80 m/ Z 8.00 43.05 8.20 8.40 8.60 47.02% Abundance #63573: 3-Pentanol, 3-methyl- 73 5000 ..... N.... 7.80 8.00 8.20__ 8.40 8.60 55 m/z 41.05 15.88% 27 45 87 39 miz-s r' "25 "20 i' । ■ 40 11" "35 r "30 11" "45 I' ' 50 " 55'' 60 ' 65 " 70" 75 " 80 ' 85 ' 90 95 100 105 110

Abundance ’’’ 73 55 7.80 8.00 8.20 8.40 8.60 43 5000 m/z 45.05 1 5.43% 27 81 II‘I‘sd"‘d"-n-"l-1"11A4***1+A11144**p00*dAA4AA*(A]*I* m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #1793: Pentane, 3-methoxy- -A A............ 73 7.80 8.00 8.20 8.40 8.60 m/ z 3 9.0.5 8.48% 5000 45

m/z-> +4733,39. — 55 " i" " I " " r " ■ r " 111' 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 11" " r " ' i ■ " ' i । ■i i" " i ■r 7.80 8.00 8.20 8.40 8.60

1941.D GCMS0208.M Fri Mar 08 16:09:34 2002 Page 1

NYC-WTC_000006384