GCMS blank sample results, Mar 8 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\l\DATA\FEB2102\LBC.D Vial: 44 Acq On : 23 Feb 2002 11:27 am Operator: Sample : gc/ms scan 1/14 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Dibutyl phthalate Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

27.70 0.22 ug/1 19460 Phenanthrene-dl0 25.73

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Dibutyl phthalate 278 C16H2204 000084-74-2 83) 2 Bis(2-methoxyethyl) phthalate 282 C14H1806 000117-82-8—78 3 1,2-Benzenedicarboxylic acid, butyl 304 C18H24O4 000084-64-0 74 4 1,2-Benzenedicarboxylic acid, dipro 250 C14H1804 000131-16-8 72 Abundance Scan 2468 (27.696 min): LBC.D (-) m/z 14 9.00 100.00% 149

5000 ............... . 41 56 76 104 27.40 27.60 27.80 28.00 ■■'I1..".'I', . ....... I'.. I 205 ‘ 223 ' I 1 ‘ ' 1 I 1 1 1 ' I 1 ' ' ‘ I * 1 1 ' I I ' 1 1 1 I ‘ 1 ' ' 1 * * 1 ' I ' m/ z 41.05 11.49% m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #72214: Dibutyl phthalate 149

5000- 27.40 27.60 27.80 28.00 m/z 150.00 10.76% 41 56 75 93 104 121 205 223 278 m/z- 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance 149

27.40 27.60 27.80 28.00____ . 5000 m/z 76.00 6.29%

41 — 57 76 93 1 04 121 160 205 223 ■ ' I ■ 1 ' 1 i ' ■ ■ 1 i ■ ■ ' ■ i 1 ' m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 I Abundance #43452:1,2-Benzenedicarboxylic acid, butyl cyclohexyl ester ■ ■ i 1 ‘ 1 ■ i ■ ’I’ ’’}’’ 149 27.40 27.60 27.80 28.00 m/ Z 56.00 5.19% 5000-

55 67 82 93 104 121 TIPITT 1*Ba0*0{*167 ........... 205 223 ■ ■ i 1 1 ' ' i ' 1 1 1 1 ' 1 ' 1 1 1 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 27.40 27.60 27.80 28.00

LBC.D GCMS0208.M Fri Mar 08 09:51:08 2002 Page 3

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