GCMS calibration data for PAHs and VOCs, Feb-Mar 2002

NYC 9/11 Public Portal Document 2UCi-. —&

Data File : C:\HPCHEM\l\DATA\FEB2102\REFC.D Vial: 45 Acq On : 23 Feb 2002 12:27 pm Operator: Sample : gc/ms scan 1/14 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 8 9:15 2002 ।Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Feb 21 16:13:52 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.33 152 212872 20.00 ug/1 -0.03 10) Naphthalene-d8 15.97 136 811383 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.29 164 447652 20.00 ug/1 -0.03 29) Phenanthrene-diO 25.73 188 634037 20.00 ug/1 -0.03 38) Chrysene-dl 2 33.80 240 428879 20.00 ug/1 -0.04 44) Perylene-dl2 38.08 264 294149 20.00 ug/1 -0.04

System Monitoring Compounds 37) 2,4-DDD 30.81 235 44338 3. 53 6.04 ug/mL 0.31 Spiked Amount 5.000 Recovery/ = 120.80% 13°1o Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.96 74 38038 4.47 ug/1 # 74 3) bis(2-Chloroethyl)ether 11.72 93 87927 6.28 ug/1 96 4) 1,3-Dichlorobenzene 12.24 146 32318 1.94 ug/1 97 5) 1,4-Dichlorobenzene 12.37 146 36156m 2.13 ug/1 6) 1,2-Dichlorobenzene 12.90 146 41161 2.55 ug/1 97 7) 2,21 -oxybis(1-Chloropropan 13.21 45 127355 6.01 ug/1 98 8) N-Nitroso-di-n-propylamine 13.60 70 62508 6.24 ug/1 89 9) Hexachloroethane 13.75 117 5650 0.83 ug/1 94 11) Nitrobenzene 14.02 77 77965 4.67 ug/1 96 12) Isophorone 14.66 82 183218 6.50 ug/1 98 13) bis(2-Chloroethoxy)methane 15.34 93 107302 6.11 ug/1 97 14) 1,2,4-Trichlorobenzene 15.86 180 35421 2.55 ug/1 95 15) Naphthalene 16.03 128 195354 4.52 ug/1 99 16) Hexachlorobutadiene 16.57 225 4742 0.57 ug/1 92 18) Hexachlorocyclopentadiene 18.78 237 547 N.D. 19) 2-Chloronaphthalene 19.54 162 123081 4.61 ug/1 98 20) Dimethylphthalate 20.63 163 216697 6.97 ug/1 99 21) 2,6-Dinitrotoluene 20.85 165 39524 5.61 ug/1 # 83 22) Acenaphthylene 20.82 152 217021 5.63 ug/1 98 23) Acenaphthene 21.38 153 156030 5.79 ug/1 98 24) 2,4-Dinitrotoluene 22.01 165 51280 5.75 ug/1 # 86 25) Diethylphthalate 22.76 149 230013 7.12 ug/1 98 26) 4-Chlorophenyl-phenylether 22.92 204 80448 5.78 ug/1 95 27) Fluorene 22.90 166 181978 6.19 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 23.38 77 203156 5.98 ug/L # 91

(#) = qualifier out of range (m) = manual integration REFC.D GCMS0208.M Fri Mar 08 09:17:22 2002 Page 1

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